A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures
Abudoureheman, M (Abudoureheman, Maierhaba); Han, SJ (Han, Shujuan); Wang, Y (Wang, Ying); Lei, BH (Lei, Bing-Hua); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume56Issue:7Pages:3939-3945
Abstract

Two polyphosphates containing two types of polymerization of the [PO4] groups, Rb3Sr2P7O22 and Cs3Sr2P7O21; were grown through a spontaneous nucleation method. Single-crystal X-ray diffraction data Were collected in order to determine their structures. Interestingly, Rb3Sr2P7O21 is the first example of two kinds of [PO3](infinity) linear Chains coexisting in one phosphate structure. However, in the structure of Cs3Sr2P7O22, the isolated [P4O12] ring and the 1D [PO3](infinity) chain can be obsetved, which is also rare in phosphates. After careful structural analysis, the alkali-metal cations have an effect on the polymerization of the [PO4] groups and make Rb3Sr2P7O21 and Cs3Sr2P7O21 crystallize in different space groups: What is more, IR spectra, UV-vis-NIR diffuse reflectance spectroscopy data, and first-principles theoretical calculations were adopted to determine the optical properties and the structure properties relationship of the compounds.

DOI10.1021/acs.inorgchem.6b03032
Indexed BySCI
WOS IDWOS:000398426000022
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4769
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorHan, SJ (Han, Shujuan); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Abudoureheman, M ,Han, SJ ,Wang, Y ,et al. A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures[J]. INORGANIC CHEMISTRY,2017,56(7):3939-3945.
APA Abudoureheman, M ,Han, SJ ,Wang, Y ,Lei, BH ,Yang, ZH ,&Pan, SL .(2017).A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures.INORGANIC CHEMISTRY,56(7),3939-3945.
MLA Abudoureheman, M ,et al."A(3)Sr(2)P(7)O(21) (A = Rb, Cs): Two Polyphosphates Based on Different Types of P-O Chains and Ring Structures".INORGANIC CHEMISTRY 56.7(2017):3939-3945.
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