The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges
Mutailipu, M (Mutailipu, Miriding); Zhang, M (Zhang, Min); Chen, YN (Chen, Yanna); Lu, XQ (Lu, Xiaoquan); Pan, SL (Pan, Shilie); Zhang, M; Pan, SL
2017
发表期刊DALTON TRANSACTIONS
卷号46期号:15页码:4923-4928
摘要Two new mixed-metal borate halides, namely, NaMg2Ba7B14O28F5 (I) and NaBa4B10O18BrF2 (II), were synthesized using the high-temperature flux method. Both structures were characterized by single-crystal X-ray diffraction, and their structures are shown to feature complicated three dimensional (3D) networks with different types of halogen-centered secondary building units (SBUs). Specifically, compound I contains three spatial fluorine-centered SBUs F(1) Ba4Mg2, F(2) Ba(Na) Ba3Mg, and F(3) Ba(Na) Ba2Mg, while compound II exhibits spatial FBa3Na and planar BrBa4 fluorine-or bromine-centered SBUs. Furthermore, four categories of halogen-centered SBUs were investigated among all the 173 available anhydrous halogen-containing borates to elaborate the role of halogen atoms to enrich the structural diversity of borates. What's more, the crystal structures, thermal stabilities, and UV-Vis-NIR diffuse reflectance spectra of synthesised compounds I and II have also been determined.
收录类别SCI
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4766
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Zhang, M; Pan, SL
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R ChinaBeijing Univ Chem Technol, State Key Lab Chem Resource Engn, North Third Ring Rd 15, Beijing 100029, Peoples R China
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Mutailipu, M ,Zhang, M ,Chen, YN ,et al. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges[J]. DALTON TRANSACTIONS,2017,46(15):4923-4928.
APA Mutailipu, M .,Zhang, M .,Chen, YN .,Lu, XQ .,Pan, SL .,...&Pan, SL.(2017).The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges.DALTON TRANSACTIONS,46(15),4923-4928.
MLA Mutailipu, M ,et al."The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges".DALTON TRANSACTIONS 46.15(2017):4923-4928.
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