LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge
Xu, DD (Xu, Dongdong); Zhang, FF (Zhang, Fangfang); Sun, YZ (Sun, Yanzhou); Yang, ZH (Yang, Zhihua); Lei, BH (Lei, Binghua); Liu, LL (Liu, Lili); Pan, SL (Pan, Shilie)
2017
发表期刊DALTON TRANSACTIONS
ISSN1477-9226
卷号46期号:1页码:193-199
摘要

A new rare-earth borate LiRb2LaB2O6 (LB-1) has been synthesized using a high-temperature solution method. Interestingly, it shares its topological structure with the famous porous material MOF-5, which is formed from Zn4O(BDC)(3) (BDC = 1,4-benzenedicarboxylate). The nodes [OZn4] and organic linkers [BDC] of MOF-5 are carefully substituted with La3+ rare-earth cations and the inorganic linkers [BO3] and [LiO4], respectively, in order to construct a pure inorganic open framework. LB-1 exhibits good thermal and water stability. Moreover, it possesses a short cut-off edge (<190 nm) and moderate birefringence (exp. 0.040@589.5 nm, cal. 0.038@589.5 nm). Further insights into the cut-off edge were given by first-principles calculations. The factors that influence the birefringence of LB-1 were discussed in view of the spatial arrangement of the [BO3] anionic groups.

DOI10.1039/c6dt04243k
收录类别SCI
WOS记录号WOS:000391570700022
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4724
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Zhang, FF (Zhang, Fangfang); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Xu, DD ,Zhang, FF ,Sun, YZ ,et al. LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge[J]. DALTON TRANSACTIONS,2017,46(1):193-199.
APA Xu, DD .,Zhang, FF .,Sun, YZ .,Yang, ZH .,Lei, BH .,...&Pan, SL .(2017).LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge.DALTON TRANSACTIONS,46(1),193-199.
MLA Xu, DD ,et al."LiRb2LaB2O6: a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge".DALTON TRANSACTIONS 46.1(2017):193-199.
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