Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method
Shi, GQ (Shi, Guoqiang); Zhang, FF (Zhang, Fangfang); Zhang, BB (Zhang, Bingbing); Hou, DW (Hou, Dianwei); Chen, XL (Chen, Xinglong); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie); Zhang, FF
2017
发表期刊INORGANIC CHEMISTRY
卷号56期号:1页码:344-350
摘要As important materials in modulating the polarization of light, birefringent crystals have attracted considerable attention and played crucial roles in the field of optical communication and the laser industry. Limited by the transparency range, few birefringent crystals can be used in the deep-ultraviolet (DUV) region, except for alpha-BaB2O4 (alpha-BBO) However, the application of a-BBO in the DUV range is restricted by the relatively high cutoff edge and low transmittance rate below 200 nm. In this paper, we design and synthesize a new fluoroborate, Na2B6O9F2, by introducing fluorine into borate system. It possesses a short cutoff edge of 169 nm and birefringence larger than 0.080 at 589.3 nm. The Na2B6O9F2 crystals with sizes up to 3.0 mm x 1.5 mm X 0.2 mm have been grown with good quality by a high-temperature solution method in the open system. First principles calculations were carried out to understand the optical properties.
DOI10.1021/acs.inorgchem.6b02269
收录类别SCI
WOS记录号WOS:000391248900040
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文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4723
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Zhang, FF
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Shi, GQ ,Zhang, FF ,Zhang, BB ,et al. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method[J]. INORGANIC CHEMISTRY,2017,56(1):344-350.
APA Shi, GQ .,Zhang, FF .,Zhang, BB .,Hou, DW .,Chen, XL .,...&Zhang, FF.(2017).Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method.INORGANIC CHEMISTRY,56(1),344-350.
MLA Shi, GQ ,et al."Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method".INORGANIC CHEMISTRY 56.1(2017):344-350.
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