Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method
Shi, GQ (Shi, Guoqiang); Zhang, FF (Zhang, Fangfang); Zhang, BB (Zhang, Bingbing); Hou, DW (Hou, Dianwei); Chen, XL (Chen, Xinglong); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationINORGANIC CHEMISTRY
Volume56Issue:1Pages:344-350
Abstract

As important materials in modulating the polarization of light, birefringent crystals have attracted considerable attention and played crucial roles in the field of optical communication and the laser industry. Limited by the transparency range, few birefringent crystals can be used in the deep-ultraviolet (DUV) region, except for alpha-BaB2O4 (alpha-BBO) However, the application of a-BBO in the DUV range is restricted by the relatively high cutoff edge and low transmittance rate below 200 nm. In this paper, we design and synthesize a new fluoroborate, Na2B6O9F2, by introducing fluorine into borate system. It possesses a short cutoff edge of 169 nm and birefringence larger than 0.080 at 589.3 nm. The Na2B6O9F2 crystals with sizes up to 3.0 mm x 1.5 mm X 0.2 mm have been grown with good quality by a high-temperature solution method in the open system. First principles calculations were carried out to understand the optical properties.

DOI10.1021/acs.inorgchem.6b02269
Indexed BySCI
WOS IDWOS:000391248900040
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4723
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, FF (Zhang, Fangfang); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Shi, GQ ,Zhang, FF ,Zhang, BB ,et al. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method[J]. INORGANIC CHEMISTRY,2017,56(1):344-350.
APA Shi, GQ .,Zhang, FF .,Zhang, BB .,Hou, DW .,Chen, XL .,...&Pan, SL .(2017).Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method.INORGANIC CHEMISTRY,56(1),344-350.
MLA Shi, GQ ,et al."Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method".INORGANIC CHEMISTRY 56.1(2017):344-350.
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