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P(NMe2)(3)-Mediated Aziridination of (mines with alpha-Ketoesters for Synthesis of Aziridine-2-carboxylates
Jiang, J (Jiang, Jin); Liu, H (Liu, Hui); Lu, CD (Lu, Chong-Dao); Xu, YJ (Xu, Yan-Jun); Lu, CD
2017
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
Volume82Issue:1Pages:811-818
AbstractAziridination of N-sulfonyI imines with alpha-ketoesters in the presence of P(NMe2)(3) is reported. Adducts derived from trivalent phosphorus reagents and alpha-ketoesters are effectively intercepted by imines, affording a range of aziridine-2-carboxylates. The diastereoselectivity of the reaction depends on steric hindrance from substituents on the substrates.
DOI10.1021/acs.joc.6b02669
Indexed BySCI
WOS IDWOS:000391781900084
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Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4721
Collection省部共建新疆特有药用资源利用重点实验室
Corresponding AuthorLu, CD
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Jiang, J ,Liu, H ,Lu, CD ,et al. P(NMe2)(3)-Mediated Aziridination of (mines with alpha-Ketoesters for Synthesis of Aziridine-2-carboxylates[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(1):811-818.
APA Jiang, J ,Liu, H ,Lu, CD ,Xu, YJ ,&Lu, CD.(2017).P(NMe2)(3)-Mediated Aziridination of (mines with alpha-Ketoesters for Synthesis of Aziridine-2-carboxylates.JOURNAL OF ORGANIC CHEMISTRY,82(1),811-818.
MLA Jiang, J ,et al."P(NMe2)(3)-Mediated Aziridination of (mines with alpha-Ketoesters for Synthesis of Aziridine-2-carboxylates".JOURNAL OF ORGANIC CHEMISTRY 82.1(2017):811-818.
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