A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response
Li, L (Li, Lin); Wang, Y (Wang, Ying); Lei, BH (Lei, Bing-Hua); Han, SJ (Han, Shujuan); Yang, ZH (Yang, Zhihua); Poeppelmeier, KR (Poeppelmeier, Kenneth R.); Pan, SL (Pan, Shilie)
2016
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume138Issue:29Pages:9101-9104
Abstract

LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very short absorption edge of A = 174 nm and generates the largest powder second harmonic generation (SHG) response for deep-UV phosphates that do not contain additional anionic groups, i.e., 2.6 times that of KH2PO4 (KDP). First-principles electronic structure analyses confirm the experimental results and suggest that the strong SHG response may originate from the aligned nonbonding O-2p orbitals. The discovery and characterization of LiCs2PO4 provide a new insight into the structure property relationships of phosphate-based nonlinear optical materials with large SHG responses and short absorption edges.

DOI10.1021/jacs.6b06053
Indexed BySCI
WOS IDWOS:000380730000028
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4647
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
Recommended Citation
GB/T 7714
Li, L ,Wang, Y ,Lei, BH ,et al. A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016,138(29):9101-9104.
APA Li, L .,Wang, Y .,Lei, BH .,Han, SJ .,Yang, ZH .,...&Pan, SL .(2016).A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,138(29),9101-9104.
MLA Li, L ,et al."A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138.29(2016):9101-9104.
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