XJIPC OpenIR  > 资源化学研究室
Direct Production of Aviation Fuel Range Hydrocarbons and Aromatics from Oleic Acid without an Added Hydrogen Donor
Tian, QR (Tian, Qiurong); Qiao, K (Qiao, Kai); Zhou, F (Zhou, Feng); Chen, KQ (Chen, Kequan); Wang, TF (Wang, Tianfu); Fu, J (Fu, Jie); Lu, XY (Lu, Xiuyang); Ouyang, PK (Ouyang, Pingkai)
2016
发表期刊ENERGY & FUELS
卷号30期号:9页码:7291-7297
摘要We herein report an atom-economic approach to produce aviation fuel range hydrocarbons and aromatics from oleic acid without an added hydrogen donor. The effects of catalyst loading, reactant loading, and reaction temperature on the conversion of oleic acid and the yields of hydrocarbons and aromatics were investigated. The conversion of oleic acid was 100%, and the yield of heptadecane (the main product) can reach 71% after 80 min at 350 degrees C. Moreover, an aromatics yield of 19% was determined, which is the critical composition of the aviation fuels due to their ability to maintain the swelling of fuel system elastomers, indicating that it is a complicated reaction system including in situ hydrogen transfer, aromatization, decarboxylation, and cracking. To probe the mechanism of the conversion of oleic acid without an added hydrogen donor, variations of the reactant and products as time elapsed at different temperatures and the reaction behavior of 1-heptadecene and stearic acid at 350 degrees C in the catalysis system were investigated. The main mechanism proposed was that oleic acid was decarboxylated to 8-heptadecene, followed by the dehydrogenation of 8-heptadecene to polyenes. Then, polyenes were cyclized to aromatics by an intramolecular Diels-Alder reaction, which provided hydrogen to hydrogenate the unreacted oleic acid to stearic acid. Finally, stearic acid was decarboxylated to heptadecane.
DOI10.1021/acs.energyfuels.6b00978
收录类别SCI
WOS记录号WOS:000383641000044
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4640
专题资源化学研究室
作者单位1.Zhejiang Univ, Coll Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
2.SINOPEC, Fushun Res Inst Petr & Petrochem, Fushun 113001, Peoples R China
3.Nanjing Tech Univ, Coll Biotechnol & Pharmaceut, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Jiangsu, Peoples R China
4.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
推荐引用方式
GB/T 7714
Tian, QR ,Qiao, K ,Zhou, F ,et al. Direct Production of Aviation Fuel Range Hydrocarbons and Aromatics from Oleic Acid without an Added Hydrogen Donor[J]. ENERGY & FUELS,2016,30(9):7291-7297.
APA Tian, QR .,Qiao, K .,Zhou, F .,Chen, KQ .,Wang, TF .,...&Ouyang, PK .(2016).Direct Production of Aviation Fuel Range Hydrocarbons and Aromatics from Oleic Acid without an Added Hydrogen Donor.ENERGY & FUELS,30(9),7291-7297.
MLA Tian, QR ,et al."Direct Production of Aviation Fuel Range Hydrocarbons and Aromatics from Oleic Acid without an Added Hydrogen Donor".ENERGY & FUELS 30.9(2016):7291-7297.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Direct Production of(1408KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Tian, QR (Tian, Qiurong)]的文章
[Qiao, K (Qiao, Kai)]的文章
[Zhou, F (Zhou, Feng)]的文章
百度学术
百度学术中相似的文章
[Tian, QR (Tian, Qiurong)]的文章
[Qiao, K (Qiao, Kai)]的文章
[Zhou, F (Zhou, Feng)]的文章
必应学术
必应学术中相似的文章
[Tian, QR (Tian, Qiurong)]的文章
[Qiao, K (Qiao, Kai)]的文章
[Zhou, F (Zhou, Feng)]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Direct Production of Aviation Fuel Range Hydrocarbons and Aromatics from Oleic Acid without an Added Hydrogen Donor.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。