Structural and Electrical Characteristics of (1-x) Pb(Lu1/2Nb1/2)O-3-xPbTiO(3) Ceramics with Low PbTiO3
Yang, XM (Yang, Xiaoming)1; He, C (He, Chao)1; Liu, Y (Liu, Ying)1; Li, XZ (Li, Xiuzhi)1; Wang, ZJ (Wang, Zujian)1; Han, SJ (Han, Shujuan)1; Pan, SL (Pan, Shilie)1; Long, XF (Long, Xifa)1
2016
发表期刊JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷号99期号:10页码:3325-3329
摘要A solid solution of (1 - x) Pb(Lu1/2Nb1/2)O-3-xPbTiO(3) with composition of 0.01 <= x <= 0.08 have been prepared successfully. XRD analysis indicates the crystal structure adopts an orthorhombic (O) phase in 0.01 <= x <= 0.06 interval and becomes the coexistence of O and rhombohedral (R) phase at x = 0.07, then turns into R phase mostly at x = 0.08. In addition, two sets of superlattice reflections due to B-site ordering and antiparallel cation displacement are distinguished by XRD and the superstructures which arise from antiparallel cation displacement disappear gradually with the increasing x. The grain size increases gradually with the increasing x, and then becomes the bimodal microstructure at x >= 0.06 due to the coexistence of O and R phase. The dielectric spectra exhibit Curie temperature decreases from 248 degrees C to 147 degrees C with increasing x from 0.01 to 0.08. As 0.01 <= x <= 0.04, the samples display typical double hysteresis loops, suggesting antiferroelectric nature, then turn into ferroelectric gradually at x = 0.05. Finally, it exhibit typical ferroelectric hysteresis loops in 0.06 <= x <= 0.08 interval.
关键词Dielectric Materials/properties Electrical Properties Ferroelectricity/ferroelectric Materials Microstructure Phase Transformations
DOI10.1111/jace.14321
收录类别SCI
WOS记录号WOS:000387223200022
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4634
专题中国科学院特殊环境功能材料与器件重点试验室
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China
2.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
4.Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
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Yang, XM ,He, C ,Liu, Y ,et al. Structural and Electrical Characteristics of (1-x) Pb(Lu1/2Nb1/2)O-3-xPbTiO(3) Ceramics with Low PbTiO3[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2016,99(10):3325-3329.
APA Yang, XM .,He, C .,Liu, Y .,Li, XZ .,Wang, ZJ .,...&Long, XF .(2016).Structural and Electrical Characteristics of (1-x) Pb(Lu1/2Nb1/2)O-3-xPbTiO(3) Ceramics with Low PbTiO3.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,99(10),3325-3329.
MLA Yang, XM ,et al."Structural and Electrical Characteristics of (1-x) Pb(Lu1/2Nb1/2)O-3-xPbTiO(3) Ceramics with Low PbTiO3".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 99.10(2016):3325-3329.
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