XJIPC OpenIR  > 材料物理与化学研究室
Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O
Liu, YQ (Liu, Yaqin); Chen, ZH (Chen, Zhaohui); Zhang, ZZ (Zhang, Zhizhong); Wang, Y (Wang, Ying); Dong, XY (Dong, Xiaoyu); Yang, ZH (Yang, Zhihua)
2016
发表期刊MATERIALS RESEARCH BULLETIN
ISSN0025-5408
卷号83期号:11页码:423-427
摘要

Single crystal of Li(H2O)(4)B(OH)(4)center dot 2H(2)O has been synthesized via hydrothermal method and its structure was determined by single crystal X-ray diffraction. The space group of Li(H2O)(4)B(OH)(4)center dot 2H(2)O is P3 with cell parameters a = b = 6.5601(4)angstrom, c= 6.1748(3)angstrom, and Z=1. The crystal lattice structure is composed of four B(OH)(4) tetrahedra, one Li(H2O)(4) tetrahedron and two isolated water molecules. Powder X-ray diffraction (XRD), infrared (IR) spectroscopy, UV-vis-IR diffuse reflectance spectroscopy, powder second harmonic generation (SHG) measurements and TG/DSC analysis were performed for the title compound. It reveals that the SHG efficiencies of Li(H2O)(4)B(OH)(4)center dot 2H(2)O is about 0.8 times that of KH2PO4 (KDP). The direction and magnitude of the dipole moments in BO4 and LiO4 units of Li(H2O)(4)B(OH)(4)center dot 2H(2)O have been quantified using the bond-valence approach, which shows that the SHG response originates from the cooperation of BO4 and LiO4 units along c axis.

关键词Optical Materials Crystal Growth Optical Properties X-ray Diffraction Crystal Structure
DOI10.1016/j.materresbull.2016.05.019
收录类别SCI
WOS记录号WOS:000382793400057
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4630
专题材料物理与化学研究室
作者单位1.Xinjiang Univ, Phys & Chem Detecting Ctr, 666 Shengli Rd, Urumqi 830046, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Xinjiang Inst Engn, Engn Dept Chem & Environm, 236 Nanchang Rd, Urumqi 830091, Peoples R China
推荐引用方式
GB/T 7714
Liu, YQ ,Chen, ZH ,Zhang, ZZ ,et al. Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O[J]. MATERIALS RESEARCH BULLETIN,2016,83(11):423-427.
APA Liu, YQ ,Chen, ZH ,Zhang, ZZ ,Wang, Y ,Dong, XY ,&Yang, ZH .(2016).Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O.MATERIALS RESEARCH BULLETIN,83(11),423-427.
MLA Liu, YQ ,et al."Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O".MATERIALS RESEARCH BULLETIN 83.11(2016):423-427.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Synthesis, structure(1210KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Liu, YQ (Liu, Yaqin)]的文章
[Chen, ZH (Chen, Zhaohui)]的文章
[Zhang, ZZ (Zhang, Zhizhong)]的文章
百度学术
百度学术中相似的文章
[Liu, YQ (Liu, Yaqin)]的文章
[Chen, ZH (Chen, Zhaohui)]的文章
[Zhang, ZZ (Zhang, Zhizhong)]的文章
必应学术
必应学术中相似的文章
[Liu, YQ (Liu, Yaqin)]的文章
[Chen, ZH (Chen, Zhaohui)]的文章
[Zhang, ZZ (Zhang, Zhizhong)]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。