Two New Crystals in LimCsnBm+nO2(m plus n) (m plus n=5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10
Li, L (Li, Lin); Han, SJ (Han, Shujuan); Lei, BH (Lei, Binghua); Dong, XY (Dong, Xiaoyu); Wu, HP (Wu, Hongping); Zhou, ZX (Zhou, Zhongxiang); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie); Han, SJ
2015
发表期刊INORGANIC CHEMISTRY
卷号54期号:15页码:7381-7387
摘要With the introduction of an alkali metal into the B-O framework, two new alkali metal borate crystals, Li5Cs2B2O14 and Li4CsB5O10, have been obtained for the first time. Both compounds obey a general formula of LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n). The two crystals have different three-dimensional (3D) framework structures composed by LiOn (n= 4, 5), CsO10, BO3, and BO4 units. Li5Cs2B7O14 crystallizes into the polar and noncentrosymmetric space group Ama2, while Li4CsB5O10 belongs to the nonpolar and centrosymmetric space group P2(1)/c. Detailed structure comparison analysis indicates that the different arrangements of the anionic groups in LimCs7-mB7O14 (m = 4, 5) and LimCs5-mB5O10 (m = 3, 4) may arise from the cation size effects, bond-valence requirements, and differences of coordination environment. In addition, in order to get better understandings of electronic structures and linear optical properties, we also carried out first-principle theoretical studies.
DOI10.1021/acs.inorgchem.5b00926
收录类别SCI
WOS记录号WOS:000359096400029
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4541
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Han, SJ
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li, L ,Han, SJ ,Lei, BH ,et al. Two New Crystals in LimCsnBm+nO2(m plus n) (m plus n=5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10[J]. INORGANIC CHEMISTRY,2015,54(15):7381-7387.
APA Li, L .,Han, SJ .,Lei, BH .,Dong, XY .,Wu, HP .,...&Han, SJ.(2015).Two New Crystals in LimCsnBm+nO2(m plus n) (m plus n=5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10.INORGANIC CHEMISTRY,54(15),7381-7387.
MLA Li, L ,et al."Two New Crystals in LimCsnBm+nO2(m plus n) (m plus n=5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10".INORGANIC CHEMISTRY 54.15(2015):7381-7387.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Two New Crystals in (2931KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Li, L (Li, Lin)]的文章
[Han, SJ (Han, Shujuan)]的文章
[Lei, BH (Lei, Binghua)]的文章
百度学术
百度学术中相似的文章
[Li, L (Li, Lin)]的文章
[Han, SJ (Han, Shujuan)]的文章
[Lei, BH (Lei, Binghua)]的文章
必应学术
必应学术中相似的文章
[Li, L (Li, Lin)]的文章
[Han, SJ (Han, Shujuan)]的文章
[Lei, BH (Lei, Binghua)]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m n) Series Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。