M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers
Zhang, XY (Zhang, Xiangyu); Li, DN (Li, Danni); Wu, HP (Wu, Hongping); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2016
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume6Issue:17Pages:14205-14210
Abstract

Two isostructural alkali calcium borates, M2Ca3B16O28 (M = Rb, Cs) have been successfully synthesized by the flux method. The two compounds crystallize in the monoclinic space group C2/c (no. 15) and feature three-dimensional open-framework layers. The M+ (M = Rb, Cs) cations occupy in-layer three-dimensional micro-pores, and the Ca2+ cations bridge the layers to form the three-dimensional network. Based on the structure analysis, it is found that M2Ca3B16O28 (M = Rb, Cs) compounds have a similar structure to that of Sr2Be2B2O7. In addition, spectroscopic properties and first-principle calculations have been carried out on the title compounds.

DOI10.1039/c5ra21011a
Indexed BySCI
WOS IDWOS:000369639400074
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4537
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, XY ,Li, DN ,Wu, HP ,et al. M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers[J]. RSC ADVANCES,2016,6(17):14205-14210.
APA Zhang, XY ,Li, DN ,Wu, HP ,Yang, ZH ,&Pan, SL .(2016).M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers.RSC ADVANCES,6(17),14205-14210.
MLA Zhang, XY ,et al."M2Ca3B16O28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers".RSC ADVANCES 6.17(2016):14205-14210.
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