Synthesis Crystal Structure. and Proserties of he Sodium Molybdate Fluoride Na3MoO4F
Zhang, XY (Zhang, Xiangyu); Li, DN (Li, Danni); Yang, ZH (Yang, Zhihua); Wu, HP (Wu, Hongping); Pan, SL (Pan, Shilie); Wu, HP
2015
发表期刊ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷号641期号:5页码:922-926
摘要The compound Na3MoO4F was synthesized by high temperature solution methods. Single-crystal X-ray diffraction analysis reveals that Na3MoO4F crystallizes in the orthorhombic space group Pram (No. 62) with lattice constants a = 5.588(2) angstrom. 6 = 7.515(3) angstrom, c = 12.876(5) angstrom. and Z = 4. The crystal structure consists of isolated MoOd groups and [FNa3](infinity) chains, which are connected by Na-O bonds to form a three-dimensional framework. A detailed structure comparison between Na3MoO4F and NaMoO3F was carried out. IR spectroscopy and bond valence sum analysis of Na3MoO4F indicate that the structure is reasonable. In addition, the electronic structure was investigated by the first-principles method,
关键词X-ray Diffraction Chemical Synthesis Electronic Hand Structure Optical Properties
DOI10.1002/zaac.201500025
收录类别SCI
WOS记录号WOS:000353034600030
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4536
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Wu, HP
作者单位Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhang, XY ,Li, DN ,Yang, ZH ,et al. Synthesis Crystal Structure. and Proserties of he Sodium Molybdate Fluoride Na3MoO4F[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(5):922-926.
APA Zhang, XY ,Li, DN ,Yang, ZH ,Wu, HP ,Pan, SL ,&Wu, HP.(2015).Synthesis Crystal Structure. and Proserties of he Sodium Molybdate Fluoride Na3MoO4F.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(5),922-926.
MLA Zhang, XY ,et al."Synthesis Crystal Structure. and Proserties of he Sodium Molybdate Fluoride Na3MoO4F".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.5(2015):922-926.
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