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题名: Na3Ba2(B3O6)(2)F: Next Generation of Deep-Ultraviolet Birefringent Materials
作者: Zhang, H (Zhang, Hui); Zhang, M (Zhang, Min); Pan, SL (Pan, Shilie); Yang, ZH (Yang, Zhihua); Wang, Z (Wang, Zheng); Bian, Q (Bian, Qiang); Hou, XL (Hou, Xueling); Yu, HW (Yu, Hongwei); Zhang, FF (Zhang, Fangfang); Wu, K (Wu, Kui); Yang, F (Yang, Feng); Peng, QJ (Peng, Qinjun); Xu, ZY (Xu, Zuyan); Chang, KB (Chang, Kelvin B.); Poeppelmeier, KR (Poeppelmeier, Kenneth R.)
通讯作者: Zhang, M
关键词: NONLINEAR-OPTICAL PROPERTIES ; HIGH-PRESSURE SYNTHESIS ; BAB2O4-NAF SYSTEM ; PHASE-EQUILIBRIA ; CRYSTAL-STRUCTURES ; GROWTH ; UV ; BORATE ; OXIDE ; COEFFICIENTS
刊名: CRYSTAL GROWTH & DESIGN
发表日期: 2015
DOI: 10.1021/cg5016912
卷: 15, 期:1, 页:523-529
收录类别: SCI
资助者: National Natural Science Foundation of China;Western Light of Chinese Academy of Sciences;973 Program of China;Main Direction Program of Knowledge Innovation of CAS;Funds for Creative Cross & Cooperation Teams of CAS;Xinjiang International Science & Technology Cooperation Program;National Science Foundation (Solid State Chemistry Award)
摘要: Birefringent materials are of great importance in optical communication and the laser industry, as they can modulate the polarization of light. Limited by their transparency range, few birefringent materials, except alpha-BaB2O4 (alpha-BBO), can be practically used in the deep ultraviolet (UV) region. However, alpha-BBO suffers from a phase transition and does not have enough transparency in the deep UV region. By introducing the relatively small alkali metal Na+ cation and the F anion to keep the favorable structural features of alpha-BBO, we report a new birefringent crystal Na3Ba2(B3O6)(2)F (NBBF), which has the desirable optical properties. NBBF not only maintains the large birefringence (Delta n = n(o) - n(e) = 0.2554-0.0750 from 175 nm to 3.35 mu m) and extends its UV cutoff edge to 175 nm (14 nm shorter than alpha-BBO) but also eliminates the phase transition and has the lowest growth temperature (820 degrees C) among birefringent materials. These results demonstrate that NBBF is an attractive candidate for the next generation of deep UV birefringent materials.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/4213
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Zhang, H ,Zhang, M ,Pan, SL ,et al. Na3Ba2(B3O6)(2)F: Next Generation of Deep-Ultraviolet Birefringent Materials[J]. CRYSTAL GROWTH & DESIGN,2015,15(1):523-529.
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