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A concise and enantioselective approach to the total synthesis of (-)-lasubine I
Liu, Shengyang; Fan, Yuping; Peng, Xinxiang; Wang, Wei; Hua, Weiyi; Akber, Haji; Liao, Lixin
2006
Source PublicationTETRAHEDRON LETTERS
ISSN0040-4039
Volume47Issue:44Pages:7681-7684
Abstract

An efficient, enantioselective total synthesis of (-)-lasubine I (1) has been achieved in an overall 8.8% yield from readily available starting materials. The important features of this approach include the creation of stereogenic centers through two sequential highly stereoselective Roush allylborations and the use of S(N)2 cyclization and ring-closing metathesis reactions for the construction of the quinolizidine skeleton.

KeywordLasubine Ring-closing Metathesis Roush Allylboration Quinolizidine
DOI10.1016/j.tetlet.2006.08.137
Indexed BySCI
WOS IDWOS:000241429400004
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4130
Collection资源化学研究室
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;China Pharmaceut Univ, Dept Med Chem, Nanjing 210009, Peoples R China;E China Univ Sci & Technol, Sch Pharm, Dept Med Chem, Shanghai 200237, Peoples R China;Univ New Mexico, Dept Chem, Albuquerque, NM 87131 USA;Chinese Acad Sci, Grad Sch, Shanghai Inst Mat Med, Shanghai Inst Biol Sci, Shanghai 201203, Peoples R China
Recommended Citation
GB/T 7714
Liu, Shengyang,Fan, Yuping,Peng, Xinxiang,et al. A concise and enantioselective approach to the total synthesis of (-)-lasubine I[J]. TETRAHEDRON LETTERS,2006,47(44):7681-7684.
APA Liu, Shengyang.,Fan, Yuping.,Peng, Xinxiang.,Wang, Wei.,Hua, Weiyi.,...&Liao, Lixin.(2006).A concise and enantioselective approach to the total synthesis of (-)-lasubine I.TETRAHEDRON LETTERS,47(44),7681-7684.
MLA Liu, Shengyang,et al."A concise and enantioselective approach to the total synthesis of (-)-lasubine I".TETRAHEDRON LETTERS 47.44(2006):7681-7684.
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