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A concise and enantioselective approach to the total synthesis of (-)-lasubine I
Liu, Shengyang; Fan, Yuping; Peng, Xinxiang; Wang, Wei; Hua, Weiyi; Akber, Haji; Liao, Lixin
2006
发表期刊TETRAHEDRON LETTERS
ISSN0040-4039
卷号47期号:44页码:7681-7684
摘要

An efficient, enantioselective total synthesis of (-)-lasubine I (1) has been achieved in an overall 8.8% yield from readily available starting materials. The important features of this approach include the creation of stereogenic centers through two sequential highly stereoselective Roush allylborations and the use of S(N)2 cyclization and ring-closing metathesis reactions for the construction of the quinolizidine skeleton.

关键词Lasubine Ring-closing Metathesis Roush Allylboration Quinolizidine
DOI10.1016/j.tetlet.2006.08.137
收录类别SCI
WOS记录号WOS:000241429400004
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4130
专题资源化学研究室
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;China Pharmaceut Univ, Dept Med Chem, Nanjing 210009, Peoples R China;E China Univ Sci & Technol, Sch Pharm, Dept Med Chem, Shanghai 200237, Peoples R China;Univ New Mexico, Dept Chem, Albuquerque, NM 87131 USA;Chinese Acad Sci, Grad Sch, Shanghai Inst Mat Med, Shanghai Inst Biol Sci, Shanghai 201203, Peoples R China
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GB/T 7714
Liu, Shengyang,Fan, Yuping,Peng, Xinxiang,et al. A concise and enantioselective approach to the total synthesis of (-)-lasubine I[J]. TETRAHEDRON LETTERS,2006,47(44):7681-7684.
APA Liu, Shengyang.,Fan, Yuping.,Peng, Xinxiang.,Wang, Wei.,Hua, Weiyi.,...&Liao, Lixin.(2006).A concise and enantioselective approach to the total synthesis of (-)-lasubine I.TETRAHEDRON LETTERS,47(44),7681-7684.
MLA Liu, Shengyang,et al."A concise and enantioselective approach to the total synthesis of (-)-lasubine I".TETRAHEDRON LETTERS 47.44(2006):7681-7684.
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