Syntheses, structures, and characterization of two new rubidium cadmium(II)/zinc(II) borates: Rb3MB5O10 (M = Cd, Zn)
Yu, Hongwei; Wu, Hongping; Pan, Shilie; Dong, Lingyun; Han, Shujun; Jiao, Anqing; Poeppelmeier, Kenneth R.
2013
发表期刊ZEITSCHRIFT FUR KRISTALLOGRAPHIE
ISSN0044-2968
卷号228期号:9页码:444-448
摘要

Two new ternary borates, Rb3MB5O10 (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X- ray diffraction. They crystallize in the same monoclinic space group P2(1)/n with lattice constants a = 10.449(11) angstrom, b = 9.414(10) angstrom, c - 11.690(12) angstrom, and beta = 105.888(11)degrees for Rb3ZnB5O10, while a = 7.6391(5) angstrom, b = 19.2304(13) angstrom, c = 7.6905(5) angstrom, and beta = 116.698(4)degrees for Rb3CdB5O10. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB5O10](infinity) (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB5O10](infinity) (M = Zn, Cd) layers, Rb3ZnB5O10 and Rb3CdB5O10 are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb3ZnB5O10 and Rb3CdB5O10, respectively.

关键词Borates Rb3znb5o10 Rb3cdb5o10 Synthesis Crystal Structure
DOI10.1524/zkri.2013.1619
收录类别SCI
WOS记录号WOS:000325697100005
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3910
专题新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
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Yu, Hongwei,Wu, Hongping,Pan, Shilie,et al. Syntheses, structures, and characterization of two new rubidium cadmium(II)/zinc(II) borates: Rb3MB5O10 (M = Cd, Zn)[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE,2013,228(9):444-448.
APA Yu, Hongwei.,Wu, Hongping.,Pan, Shilie.,Dong, Lingyun.,Han, Shujun.,...&Poeppelmeier, Kenneth R..(2013).Syntheses, structures, and characterization of two new rubidium cadmium(II)/zinc(II) borates: Rb3MB5O10 (M = Cd, Zn).ZEITSCHRIFT FUR KRISTALLOGRAPHIE,228(9),444-448.
MLA Yu, Hongwei,et al."Syntheses, structures, and characterization of two new rubidium cadmium(II)/zinc(II) borates: Rb3MB5O10 (M = Cd, Zn)".ZEITSCHRIFT FUR KRISTALLOGRAPHIE 228.9(2013):444-448.
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