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题名: Pb<inf>2</inf>B<inf>5</inf>O<inf>9</inf>Cl: A chloride borate with second harmonic generation effect
作者: Chen, Zhaohui (1) ; Pan, Shilie (1) ; Yang, Zhihua (1) ; Dong, Xiaoyu (1) ; Su, Xin (1) ; Yang, Yun (1)
通讯作者: Pan, S.(slpan@ms.xjb.ac.cn)
刊名: Journal of Materials Science
发表日期: 2013
卷: 48, 期:6, 页:2590-2596
收录类别: SCI ; EI
部门归属: (1) Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830011, China ; (2) Physical and Chemical Detecting Center, Xinjiang University, Urumqi 830046, China ; (3) University of Chinese Academy of Sciences, Beijing 100049, China
摘要: Single crystal of Pb2B5O9Cl with sizes up to 25 × 6 × 2 mm3 has been obtained successfully using PbCl2-H3BO3 flux system by the high temperature solution method for the first time. It crystallizes in noncentrosymmetric orthorhombic space group Pnn2 (No. 34). It produces second harmonic generation (SHG) intensity about 4 times that of KH2PO4 (KDP) and is phase matchable. The origin and magnitude of the strong SHG effect was discussed. Band structures, density of states, and dipole moment calculations were calculated. © 2012 Springer Science+Business Media New York.
英文摘要: Single crystal of Pb2B5O9Cl with sizes up to 25 × 6 × 2 mm3 has been obtained successfully using PbCl2-H3BO3 flux system by the high temperature solution method for the first time. It crystallizes in noncentrosymmetric orthorhombic space group Pnn2 (No. 34). It produces second harmonic generation (SHG) intensity about 4 times that of KH2PO4 (KDP) and is phase matchable. The origin and magnitude of the strong SHG effect was discussed. Band structures, density of states, and dipole moment calculations were calculated. © 2012 Springer Science+Business Media New York.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3897
Appears in Collections:中国科学院新疆理化技术研究所(2002年以前数据)_期刊论文

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Chen, Zhaohui (1); Pan, Shilie (1); Yang, Zhihua (1); Dong, Xiaoyu (1); Su, Xin (1); Yang, Yun (1).Pb2B5O9Cl: A chloride borate with second harmonic generation effect,Journal of Materials Science,2013,48(6):2590-2596
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