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题名: Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation
作者: Wang, Hong-Tu ; Lu, Chong-Dao
关键词: Dirhodium(II) ; Catalysis ; Oxidation ; Cycloaddition ; Pyrrolo[2,1-a]isoquinolines
刊名: TETRAHEDRON LETTERS
发表日期: 2013
卷: 54, 期:23, 页:3015-3018
收录类别: SCI
部门归属: [Wang, Hong-Tu ; Lu, Chong-Dao] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China. [Wang, Hong-Tu] Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
摘要: Azomethine ylides have been efficiently generated via Rh-2(cap)(4)-catalyzed oxidation of tetrahydroisoquinoline derivatives in the presence of base. The ylides are trapped in situ via [3+2] cycloaddition with dipolarophiles and subjected to oxidative aromatization facilitated by N-bromosuccinimide to provide 3,4-dihydropyrrolo[2,1-a]isoquinoline derivatives in moderate to excellent yields. (C) 2013 Elsevier Ltd. All rights reserved.
英文摘要: Azomethine ylides have been efficiently generated via Rh-2(cap)(4)-catalyzed oxidation of tetrahydroisoquinoline derivatives in the presence of base. The ylides are trapped in situ via [3+2] cycloaddition with dipolarophiles and subjected to oxidative aromatization facilitated by N-bromosuccinimide to provide 3,4-dihydropyrrolo[2,1-a]isoquinoline derivatives in moderate to excellent yields. (C) 2013 Elsevier Ltd. All rights reserved.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3886
Appears in Collections:中国科学院新疆理化技术研究所(2002年以前数据)_期刊论文

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Wang, Hong-Tu;Lu, Chong-Dao.Synthesis of 3,4-dihydropyrrolo[2,1-a]isoquinolines based on [3+2] cycloaddition initiated by Rh-2(cap)(4)-catalyzed oxidation,TETRAHEDRON LETTERS,2013,54(23):3015-3018
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