中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 中国科学院新疆理化技术研究所(2002年以前数据)  > 期刊论文
题名: Syntheses, crystal structures, and optical properties of Pb <inf>6</inf>B<inf>3</inf>O<inf>10</inf>X (X = F, Cl, Br)
作者: Dong, Lingyun (1) ; Pan, Shilie (1) ; Wu, Hongping (1) ; Su, Xin (1) ; Yu, Hongwei (1) ; Wang, Ying (1) ; Chen, Zhaohui (1) ; Huang, Zhenjun (1) ; Yang, Zhihua (1)
通讯作者: Pan, S.(slpan@ms.xjb.ac.cn)
关键词: Pb6B3O10X (X=F, Cl, Br) ; Oxyborates ; Crystal structures ; Syntheses ; Optical properties
刊名: Journal of Solid State Chemistry
发表日期: 2013
卷: 204, 页:64-69
收录类别: SCI ; EI
部门归属: (1) Xinjiang Technical Institute of Physics and Chemistry, Key Laboratory of Functional Materials and Devices under Special Environments, CAS, China ; (2) Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China ; (3) University of Chinese Academy of Sciences, Beijing 100049, China
摘要: A series of lead-containing halogen oxyborates, Pb6B 3O10X (X = F, Cl, Br), have been grown by high-temperature solution method and their crystal structures were determined by single-crystal X-ray diffraction. They are isostructural and crystallize in the space group Pbcm of the orthorhombic crystal system. The crystal structures are dominated by one-dimensional [(Pb4O)(BO3) 3] "Zig-Zag"-chains, while the remaining Pb atoms and X (X=F, Cl, Br) atoms are filled to balance the charge. Compared with the previously reported compound Pb4O(BO3)2 (the molecular formula Pb4O(BO3)2 can be regarded as Pb6B3O10.5) with the space group Aba2, the structures of Pb6B3O10X (X = F, Cl, Br) are completely different from that of Pb4O(BO3)2. IR spectroscopy, UV-vis-NIR diffuse reflectance spectroscopy, thermal analysis, and theoretical calculations were also performed on the reported materials. Crown Copyright © 2013 Published by Elsevier Inc.
英文摘要: A series of lead-containing halogen oxyborates, Pb6B 3O10X (X = F, Cl, Br), have been grown by high-temperature solution method and their crystal structures were determined by single-crystal X-ray diffraction. They are isostructural and crystallize in the space group Pbcm of the orthorhombic crystal system. The crystal structures are dominated by one-dimensional [(Pb4O)(BO3) 3] "Zig-Zag"-chains, while the remaining Pb atoms and X (X=F, Cl, Br) atoms are filled to balance the charge. Compared with the previously reported compound Pb4O(BO3)2 (the molecular formula Pb4O(BO3)2 can be regarded as Pb6B3O10.5) with the space group Aba2, the structures of Pb6B3O10X (X = F, Cl, Br) are completely different from that of Pb4O(BO3)2. IR spectroscopy, UV-vis-NIR diffuse reflectance spectroscopy, thermal analysis, and theoretical calculations were also performed on the reported materials. Crown Copyright © 2013 Published by Elsevier Inc.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3878
Appears in Collections:中国科学院新疆理化技术研究所(2002年以前数据)_期刊论文

Files in This Item:

There are no files associated with this item.


Recommended Citation:
Dong, Lingyun (1); Pan, Shilie (1); Wu, Hongping (1); Su, Xin (1); Yu, Hongwei (1); Wang, Ying (1); Chen, Zhaohui (1); Huang, Zhenjun (1); Yang, Zhihua (1).Syntheses, crystal structures, and optical properties of Pb 6B3O10X (X = F, Cl, Br),Journal of Solid State Chemistry,2013,204():64-69
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Dong, Lingyun (1)]'s Articles
[Pan, Shilie (1)]'s Articles
[Wu, Hongping (1)]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Dong, Lingyun (1)]‘s Articles
[Pan, Shilie (1)]‘s Articles
[Wu, Hongping (1)]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace