Special (1)(infinity)[OPb2] Chains and (1)(infinity)[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb-2(O4Pb8)(BO3)(3)Br-3 and Pb-2(O8Pb12)(BO3)(2)Br-6
Dong, Lingyun; Pan, Shilie; Wang, Ying; Yu, Hongwei; Dong, Xiaoyu; Han, Shujuan; Zhang, Min; Pan, SL
2013
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume52Issue:19Pages:11377-11384
Abstract

The structures of two new lead-containing oxyborate bromines, Pb-2(O4Pb8)(BO3)(3)Br-3 and Pb-2(O8Pb12)(BO3)(2)Br-6 (2), are determined by single-crystal X-ray diffraction for the first time. Both of them crystallize in the space group C2/c of the monoclinic crystal system. Although the two compounds have the same type of fundmental building units (FBUs), the OPb4, anion-centered tetrahedra and BO3 triangles, they exhibit different connection modes. Compound 1 consists of single (1)(infinity)[OPb2] chains, while compound 2 possesses (1)(infinity)[O2Pb3] ribbons. Interestingly, large Br atoms profoundly influence the conformation of polyions based on the OPb4 anion-centered tetrahedra, resulting in single (1)(infinity)[OPb2] chains linked up by finite zweier chains with four OPb4 tetrahedra via the opposite edges in compound 1 and (1)(infinity)[O2Pb3] ribbons with sequential condensation of OPb2 chains in compound 2. A detailed description of the effect of large Br atoms on the conformation of polyions is discussed. IR spectroscopy, UV-vis-NIR diffuse reflectance spectroscopy, and thermal analysis are also performed on the reported materials.

DOI10.1021/ic401655h
Indexed BySCI
WOS IDWOS:000326319800081
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3861
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan, SL
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Dong, Lingyun,Pan, Shilie,Wang, Ying,et al. Special (1)(infinity)[OPb2] Chains and (1)(infinity)[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb-2(O4Pb8)(BO3)(3)Br-3 and Pb-2(O8Pb12)(BO3)(2)Br-6[J]. INORGANIC CHEMISTRY,2013,52(19):11377-11384.
APA Dong, Lingyun.,Pan, Shilie.,Wang, Ying.,Yu, Hongwei.,Dong, Xiaoyu.,...&Pan, SL.(2013).Special (1)(infinity)[OPb2] Chains and (1)(infinity)[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb-2(O4Pb8)(BO3)(3)Br-3 and Pb-2(O8Pb12)(BO3)(2)Br-6.INORGANIC CHEMISTRY,52(19),11377-11384.
MLA Dong, Lingyun,et al."Special (1)(infinity)[OPb2] Chains and (1)(infinity)[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb-2(O4Pb8)(BO3)(3)Br-3 and Pb-2(O8Pb12)(BO3)(2)Br-6".INORGANIC CHEMISTRY 52.19(2013):11377-11384.
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