Noncentrosymmetric Cubic CsCdBO3 with Bichromophore
Yu, Hongwei; Wu, Hongping; Pan, Shilie; Zhang, Bingbing; Wen, Ming; Yang, Zhihua; Li, Hongyi; Jiang, Xiangzhan

The noncentrosymmetric borate CsCdBO3 was synthesized by a solid-state reaction, and its structure was determined by single-crystal X-ray diffraction. The crystal structure is a complicated three-dimensional network composed of CdO6 octahedra, CsO6 octahedra, and BO3 triangles. Interestingly, CsCdBO3 crystallizes in the cubic space group P2(1)3, which is quite rare for borate-containing anisotropic polarized planar BO3 groups. Furthermore, the IR spectrum confirms the presence of BO3 groups. Second harmonic generation (SHG) measurements on powder samples reveal that the SHG response of CsCdBO3 is approximately 0.5x KDP (KH2PO4). Thermal analysis and UV/Vis/NIR diffuse reflectance spectroscopy data, as well as electronic band structure calculations, are also reported.

KeywordNoncentrosymmetry Borates Nonlinear Optics Shg Structure Elucidation
Indexed BySCI
WOS IDWOS:000329484000003
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Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China; Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yu, Hongwei,Wu, Hongping,Pan, Shilie,et al. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013,2013(32):5528-5533.
APA Yu, Hongwei.,Wu, Hongping.,Pan, Shilie.,Zhang, Bingbing.,Wen, Ming.,...&Jiang, Xiangzhan.(2013).Noncentrosymmetric Cubic CsCdBO3 with Bichromophore.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(32),5528-5533.
MLA Yu, Hongwei,et al."Noncentrosymmetric Cubic CsCdBO3 with Bichromophore".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2013.32(2013):5528-5533.
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