Noncentrosymmetric Cubic CsCdBO3 with Bichromophore
Yu, Hongwei; Wu, Hongping; Pan, Shilie; Zhang, Bingbing; Wen, Ming; Yang, Zhihua; Li, Hongyi; Jiang, Xiangzhan
2013
发表期刊EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
卷号2013期号:32页码:5528-5533
摘要

The noncentrosymmetric borate CsCdBO3 was synthesized by a solid-state reaction, and its structure was determined by single-crystal X-ray diffraction. The crystal structure is a complicated three-dimensional network composed of CdO6 octahedra, CsO6 octahedra, and BO3 triangles. Interestingly, CsCdBO3 crystallizes in the cubic space group P2(1)3, which is quite rare for borate-containing anisotropic polarized planar BO3 groups. Furthermore, the IR spectrum confirms the presence of BO3 groups. Second harmonic generation (SHG) measurements on powder samples reveal that the SHG response of CsCdBO3 is approximately 0.5x KDP (KH2PO4). Thermal analysis and UV/Vis/NIR diffuse reflectance spectroscopy data, as well as electronic band structure calculations, are also reported.

关键词Noncentrosymmetry Borates Nonlinear Optics Shg Structure Elucidation
DOI10.1002/ejic.201301075
收录类别SCI
WOS记录号WOS:000329484000003
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3855
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China; Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Yu, Hongwei,Wu, Hongping,Pan, Shilie,et al. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013,2013(32):5528-5533.
APA Yu, Hongwei.,Wu, Hongping.,Pan, Shilie.,Zhang, Bingbing.,Wen, Ming.,...&Jiang, Xiangzhan.(2013).Noncentrosymmetric Cubic CsCdBO3 with Bichromophore.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(32),5528-5533.
MLA Yu, Hongwei,et al."Noncentrosymmetric Cubic CsCdBO3 with Bichromophore".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2013.32(2013):5528-5533.
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