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XJIPC OpenIR  > 新疆维吾尔自治区电子信息材料与器件重点实验室  > 期刊论文
题名: Noncentrosymmetric Cubic CsCdBO3 with Bichromophore
作者: Yu, Hongwei; Wu, Hongping; Pan, Shilie; Zhang, Bingbing; Wen, Ming; Yang, Zhihua; Li, Hongyi; Jiang, Xiangzhan
关键词: Noncentrosymmetry ; Borates ; Nonlinear optics ; SHG ; Structure elucidation
刊名: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
发表日期: 2013
DOI: 10.1002/ejic.201301075
卷: 2013, 期:32, 页:5528-5533
收录类别: SCI
摘要: The noncentrosymmetric borate CsCdBO3 was synthesized by a solid-state reaction, and its structure was determined by single-crystal X-ray diffraction. The crystal structure is a complicated three-dimensional network composed of CdO6 octahedra, CsO6 octahedra, and BO3 triangles. Interestingly, CsCdBO3 crystallizes in the cubic space group P2(1)3, which is quite rare for borate-containing anisotropic polarized planar BO3 groups. Furthermore, the IR spectrum confirms the presence of BO3 groups. Second harmonic generation (SHG) measurements on powder samples reveal that the SHG response of CsCdBO3 is approximately 0.5x KDP (KH2PO4). Thermal analysis and UV/Vis/NIR diffuse reflectance spectroscopy data, as well as electronic band structure calculations, are also reported.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3855
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China; Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Yu, Hongwei,Wu, Hongping,Pan, Shilie,et al. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013,2013(32):5528-5533.
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