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题名: Quadruply Hydrogen Bonding Modules-Versatile Building Blocks for Polymeric Material Design-Beyond Entanglements
作者: Eli, Wumanjiang; Zhang, Yagang
通讯作者: Zhang, YG
关键词: Quadruply hydrogen-bonding ; Self-assembly ; Stimuli-responsive polymers ; Functionalized polymer
刊名: CURRENT ORGANIC CHEMISTRY
发表日期: 2013
卷: 17, 期:24, 页:3064-3072
收录类别: SCI
摘要: Hydrogen bonding facilitated self-assembly is an appealing strategy for constructing advanced molecular architecture. Arrays of quadruply hydrogen-bonding (QHB) modules are especially appealing due to the reason that it features extremely strong yet reversible and dynamic interactions. This review focus on the design and development of polymeric materials utilizing QHB arrays such as 2-ureido- 4[1H]-pyrimidone (UPy), butylurea of guanosine (UG), deazapterin (DeAP), 2,7-diamido-1,8-naphthyridine (DAN) and 7-deazaguanine urea (DeUG). Investigating QHB interaction at molecular level and evaluate the physical and chemical properties of the resulting material in solution and bulk are discussed. Specific examples highlighted in this review demonstrate how QHB modules are used and incorporated into polymer matrix to yield stimuli-responsive functionalized polymer. It is discussed how QHB modules providing extra interactions which are responsive under mechanical stress. The interactions associated with QHB modules could be effective adhesion promoters and source of energy dissipater and can facilitate development of functional polymers and smart materials such as stimuli-responsive polymers, novel interpenetrating polymers, polymer blends and fiber/particle reinforced polymer nano-composite.
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3850
Appears in Collections:新疆维吾尔自治区精细化工工程技术研究中心_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Xinjiang, Peoples R China; Univ Illinois, Dept Chem, Urbana, IL 61801 USA

Recommended Citation:
Eli, Wumanjiang,Zhang, Yagang. Quadruply Hydrogen Bonding Modules-Versatile Building Blocks for Polymeric Material Design-Beyond Entanglements[J]. CURRENT ORGANIC CHEMISTRY,2013,17(24):3064-3072.
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