Quadruply Hydrogen Bonding Modules-Versatile Building Blocks for Polymeric Material Design-Beyond Entanglements
Eli, Wumanjiang; Zhang, Yagang
2013
Source PublicationCURRENT ORGANIC CHEMISTRY
ISSN1385-2728
Volume17Issue:24Pages:3064-3072
Abstract

Hydrogen bonding facilitated self-assembly is an appealing strategy for constructing advanced molecular architecture. Arrays of quadruply hydrogen-bonding (QHB) modules are especially appealing due to the reason that it features extremely strong yet reversible and dynamic interactions. This review focus on the design and development of polymeric materials utilizing QHB arrays such as 2-ureido- 4[1H]-pyrimidone (UPy), butylurea of guanosine (UG), deazapterin (DeAP), 2,7-diamido-1,8-naphthyridine (DAN) and 7-deazaguanine urea (DeUG). Investigating QHB interaction at molecular level and evaluate the physical and chemical properties of the resulting material in solution and bulk are discussed. Specific examples highlighted in this review demonstrate how QHB modules are used and incorporated into polymer matrix to yield stimuli-responsive functionalized polymer. It is discussed how QHB modules providing extra interactions which are responsive under mechanical stress. The interactions associated with QHB modules could be effective adhesion promoters and source of energy dissipater and can facilitate development of functional polymers and smart materials such as stimuli-responsive polymers, novel interpenetrating polymers, polymer blends and fiber/particle reinforced polymer nano-composite.

KeywordQuadruply Hydrogen-bonding Self-assembly Stimuli-responsive Polymers Functionalized Polymer
DOI10.2174/13852728113179990028
Indexed BySCI
WOS IDWOS:000328902400012
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3850
Collection新疆维吾尔自治区精细化工工程技术研究中心
资源化学研究室
Corresponding AuthorZhang, Yagang
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Xinjiang, Peoples R China; Univ Illinois, Dept Chem, Urbana, IL 61801 USA
Recommended Citation
GB/T 7714
Eli, Wumanjiang,Zhang, Yagang. Quadruply Hydrogen Bonding Modules-Versatile Building Blocks for Polymeric Material Design-Beyond Entanglements[J]. CURRENT ORGANIC CHEMISTRY,2013,17(24):3064-3072.
APA Eli, Wumanjiang,&Zhang, Yagang.(2013).Quadruply Hydrogen Bonding Modules-Versatile Building Blocks for Polymeric Material Design-Beyond Entanglements.CURRENT ORGANIC CHEMISTRY,17(24),3064-3072.
MLA Eli, Wumanjiang,et al."Quadruply Hydrogen Bonding Modules-Versatile Building Blocks for Polymeric Material Design-Beyond Entanglements".CURRENT ORGANIC CHEMISTRY 17.24(2013):3064-3072.
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