中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 中国科学院特殊环境功能材料与器件重点试验室  > 期刊论文
题名: Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block
作者: Fangyuan Zhang; Qun Jing; Fangfang Zhang; Pan, Shilie; Yang, Zhihua; Han, Jian; Zhang, Min; Han, Shujuan
通讯作者: Zhang, F.(ffzhang@ms.xjb.ac.cn)
刊名: Journal of Materials Chemistry C
发表日期: 2014
DOI: 10.1039/c3tc31420k
卷: 2, 期:4, 页:667-674
收录类别: SCI
摘要: A new ultraviolet (UV) nonlinear optical (NLO) crystal Sr4B 10O18(OH)2·2H2O has been synthesized using the hydrothermal method. It crystallizes in the triclinic space group P1 (no. 1) with lattice constants a = 6.4991(6) A˚, b = 6.5059(6) A˚, c = 11.3175(11) A˚, α = 88.458(6)°, β = 86.019(5)°, γ = 61.351(5)°, Z = 1. The fundamental building block of the structure is a [B10O23]16- unit which consists of two stereo-isomeric configurations of [B5O 12]9- groups. The structure exhibits a ∞[B10O18]6- three dimensional network with 9-membered tunnels along the b-axis where the Sr cation, OH anion and H2O molecule are located. Powder second harmonic generation (SHG) measurements indicate that Sr4B10O18(OH) 2·2H2O is type-I phase-matchable and displays a SHG response of about 2 × KH2PO4. The UV-Vis-NIR diffuse reflectance spectrum shows that its cutoff edge is lower than 190 nm. Density functional theory (DFT) calculations on electronic structures and SHG coefficients confirm the experimental results.
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3844
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
Sr4B10O18(OH)2·2H2O a new UV nonlinear optical material with a [B10O23]16− building block .pdf(964KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Fangyuan Zhang,Qun Jing,Fangfang Zhang,et al. Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block[J]. Journal of Materials Chemistry C,2014,2(4):667-674.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Fangyuan Zhang]'s Articles
[Qun Jing]'s Articles
[Fangfang Zhang]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Fangyuan Zhang]‘s Articles
[Qun Jing]‘s Articles
[Fangfang Zhang]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: Sr4B10O18(OH)2·2H2O a new UV nonlinear optical material with a [B10O23]16− building block .pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace