Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block
Fangyuan Zhang; Qun Jing; Fangfang Zhang; Pan, Shilie; Yang, Zhihua; Han, Jian; Zhang, Min; Han, Shujuan; Zhang, F.
2014
发表期刊Journal of Materials Chemistry C
ISSN20507534
卷号2期号:4页码:667-674
摘要A new ultraviolet (UV) nonlinear optical (NLO) crystal Sr4B 10O18(OH)2·2H2O has been synthesized using the hydrothermal method. It crystallizes in the triclinic space group P1 (no. 1) with lattice constants a = 6.4991(6) A˚, b = 6.5059(6) A˚, c = 11.3175(11) A˚, α = 88.458(6)°, β = 86.019(5)°, γ = 61.351(5)°, Z = 1. The fundamental building block of the structure is a [B10O23]16- unit which consists of two stereo-isomeric configurations of [B5O 12]9- groups. The structure exhibits a ∞[B10O18]6- three dimensional network with 9-membered tunnels along the b-axis where the Sr cation, OH anion and H2O molecule are located. Powder second harmonic generation (SHG) measurements indicate that Sr4B10O18(OH) 2·2H2O is type-I phase-matchable and displays a SHG response of about 2 × KH2PO4. The UV-Vis-NIR diffuse reflectance spectrum shows that its cutoff edge is lower than 190 nm. Density functional theory (DFT) calculations on electronic structures and SHG coefficients confirm the experimental results.
DOI10.1039/c3tc31420k
收录类别SCI
WOS记录号WOS:000329069900010
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文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3844
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Zhang, F.
作者单位Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Fangyuan Zhang,Qun Jing,Fangfang Zhang,et al. Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block[J]. Journal of Materials Chemistry C,2014,2(4):667-674.
APA Fangyuan Zhang.,Qun Jing.,Fangfang Zhang.,Pan, Shilie.,Yang, Zhihua.,...&Zhang, F..(2014).Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block.Journal of Materials Chemistry C,2(4),667-674.
MLA Fangyuan Zhang,et al."Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block".Journal of Materials Chemistry C 2.4(2014):667-674.
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