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题名: Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block
作者: Fangyuan Zhang; Qun Jing; Fangfang Zhang; Pan, Shilie; Yang, Zhihua; Han, Jian; Zhang, Min; Han, Shujuan
通讯作者: Zhang, F.
刊名: Journal of Materials Chemistry C
发表日期: 2014
DOI: 10.1039/c3tc31420k
卷: 2, 期:4, 页:667-674
收录类别: SCI
英文摘要: A new ultraviolet (UV) nonlinear optical (NLO) crystal Sr4B 10O18(OH)2·2H2O has been synthesized using the hydrothermal method. It crystallizes in the triclinic space group P1 (no. 1) with lattice constants a = 6.4991(6) A˚, b = 6.5059(6) A˚, c = 11.3175(11) A˚, α = 88.458(6)°, β = 86.019(5)°, γ = 61.351(5)°, Z = 1. The fundamental building block of the structure is a [B10O23]16- unit which consists of two stereo-isomeric configurations of [B5O 12]9- groups. The structure exhibits a ∞[B10O18]6- three dimensional network with 9-membered tunnels along the b-axis where the Sr cation, OH anion and H2O molecule are located. Powder second harmonic generation (SHG) measurements indicate that Sr4B10O18(OH) 2·2H2O is type-I phase-matchable and displays a SHG response of about 2 × KH2PO4. The UV-Vis-NIR diffuse reflectance spectrum shows that its cutoff edge is lower than 190 nm. Density functional theory (DFT) calculations on electronic structures and SHG coefficients confirm the experimental results.
WOS记录号: WOS:000329069900010
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3844
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Fangyuan Zhang,Qun Jing,Fangfang Zhang,et al. Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block[J]. Journal of Materials Chemistry C,2014,2(4):667-674.
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