Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block
Fangyuan Zhang; Qun Jing; Fangfang Zhang; Pan, Shilie; Yang, Zhihua; Han, Jian; Zhang, Min; Han, Shujuan; Zhang, F.
2014
Source PublicationJournal of Materials Chemistry C
ISSN2050-7526
Volume2Issue:4Pages:667-674
Abstract

A new ultraviolet (UV) nonlinear optical (NLO) crystal Sr4B 10O18(OH)2·2H2O has been synthesized using the hydrothermal method. It crystallizes in the triclinic space group P1 (no. 1) with lattice constants a = 6.4991(6) A˚, b = 6.5059(6) A˚, c = 11.3175(11) A˚, α = 88.458(6)°, β = 86.019(5)°, γ = 61.351(5)°, Z = 1. The fundamental building block of the structure is a [B10O23]16- unit which consists of two stereo-isomeric configurations of [B5O 12]9- groups. The structure exhibits a ∞[B10O18]6- three dimensional network with 9-membered tunnels along the b-axis where the Sr cation, OH anion and H2O molecule are located. Powder second harmonic generation (SHG) measurements indicate that Sr4B10O18(OH) 2·2H2O is type-I phase-matchable and displays a SHG response of about 2 × KH2PO4. The UV-Vis-NIR diffuse reflectance spectrum shows that its cutoff edge is lower than 190 nm. Density functional theory (DFT) calculations on electronic structures and SHG coefficients confirm the experimental results.

DOI10.1039/c3tc31420k
Indexed BySCI
WOS IDWOS:000329069900010
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3844
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorFangfang Zhang; Zhang, F.
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
2.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Fangyuan Zhang,Qun Jing,Fangfang Zhang,et al. Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block[J]. Journal of Materials Chemistry C,2014,2(4):667-674.
APA Fangyuan Zhang.,Qun Jing.,Fangfang Zhang.,Pan, Shilie.,Yang, Zhihua.,...&Zhang, F..(2014).Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block.Journal of Materials Chemistry C,2(4),667-674.
MLA Fangyuan Zhang,et al."Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block".Journal of Materials Chemistry C 2.4(2014):667-674.
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