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题名: Synthesis of carbonated cotton seed oil and its application as lubricating base oil
作者: Zhang, Letao; Luo, Yanping; Hou, Zhenshan; He, Zhenhong; Eli, Wumanjiang
关键词: Carbonates ; Vegetable oil ; Lubricating base oil ; Tribological behavior ; Thermal and oxidative stability
刊名: JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
发表日期: 2014
DOI: 10.1007/s11746-013-2358-1
卷: 91, 期:1, 页:143-150
收录类别: SCI
摘要: Epoxidized cotton seed oil (ECSO) was conveniently synthesized from cotton seed oil (CSO) in the presence of hydrogen peroxide, formic acid, and phosphoric acid. Then the ECSO was converted into carbonated cotton seed oil (CCSO) by reacting with CO2 using tetrabutylammonium bromide as a catalyst. The reaction conditions including reaction temperature, pressure, reaction time and the amount of catalyst were examined. In addition, the final product (CCSO) from cyclic addition reaction was characterized by FT-IR, 1H NMR and TGA. Compared with CSO and ECSO, CCSO showed excellent thermal and oxidation stability. Additionally, the CCSO's properties of extreme pressure, anti-wear and friction reduction were tested and analyzed. The results indicated that it could be used as potential lubricating base oil.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3843
Appears in Collections:新疆维吾尔自治区精细化工工程技术研究中心_期刊论文

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作者单位: Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi 830011, China

Recommended Citation:
Zhang, Letao,Luo, Yanping,Hou, Zhenshan,et al. Synthesis of carbonated cotton seed oil and its application as lubricating base oil[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY,2014,91(1):143-150.
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文件名: Synthesis of Carbonated Cotton Seed Oil and Its Application as Lubricating Base Oil .pdf
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