Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain
YuHongwei; WuHongping; PanShilie; ZhangBingbing; DongLingyun; HanShujuan; YangZhihua
2014
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume38Issue:1Pages:285-291
AbstractA new lead zinc borate, Pb4Zn2B10O21, has been synthesized and the crystal structure was determined by single crystal X-ray diffraction. It crystallizes in the orthorhombic group Pbcn with a = 14.6062(15) angstrom, b = 17.4899(16) angstrom, c = 13.2962(15) angstrom, Z = 8. Interestingly, in the crystal structure, a new B-O building unit [B10O24] group is observed and the four different coordinated Pb atoms are connected with each other by sharing a corner, edge or face to form an interesting regular [Pb4O12](infinity) chain. The DSC analysis proves that Pb4Zn2B10O21 melts congruently. First-principles electronic structure calculation shows that the calculated band gap of Pb4Zn2B10O21 is 3.53 eV, which is in good agreement with the experimental value measured from the UV-vis-NIR absorption spectrum, and the observed absorption peak is assigned as a charge transfer from O 2p states to Pb 6p states.
DOI10.1039/c3nj00893b
Indexed BySCI
WOS IDWOS:000329886900037
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3842
Collection中国科学院特殊环境功能材料与器件重点试验室
AffiliationChinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
YuHongwei,WuHongping,PanShilie,et al. Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain[J]. NEW JOURNAL OF CHEMISTRY,2014,38(1):285-291.
APA YuHongwei.,WuHongping.,PanShilie.,ZhangBingbing.,DongLingyun.,...&YangZhihua.(2014).Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain.NEW JOURNAL OF CHEMISTRY,38(1),285-291.
MLA YuHongwei,et al."Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain".NEW JOURNAL OF CHEMISTRY 38.1(2014):285-291.
Files in This Item:
File Name/Size DocType Version Access License
Pb4Zn2B10O21 a congr(2084KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[YuHongwei]'s Articles
[WuHongping]'s Articles
[PanShilie]'s Articles
Baidu academic
Similar articles in Baidu academic
[YuHongwei]'s Articles
[WuHongping]'s Articles
[PanShilie]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[YuHongwei]'s Articles
[WuHongping]'s Articles
[PanShilie]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Pb4Zn2B10O21 a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12]∞ chain.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.