Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain
YuHongwei; WuHongping; PanShilie; ZhangBingbing; DongLingyun; HanShujuan; YangZhihua
2014
发表期刊NEW JOURNAL OF CHEMISTRY
ISSN1144-0546
卷号38期号:1页码:285-291
摘要A new lead zinc borate, Pb4Zn2B10O21, has been synthesized and the crystal structure was determined by single crystal X-ray diffraction. It crystallizes in the orthorhombic group Pbcn with a = 14.6062(15) angstrom, b = 17.4899(16) angstrom, c = 13.2962(15) angstrom, Z = 8. Interestingly, in the crystal structure, a new B-O building unit [B10O24] group is observed and the four different coordinated Pb atoms are connected with each other by sharing a corner, edge or face to form an interesting regular [Pb4O12](infinity) chain. The DSC analysis proves that Pb4Zn2B10O21 melts congruently. First-principles electronic structure calculation shows that the calculated band gap of Pb4Zn2B10O21 is 3.53 eV, which is in good agreement with the experimental value measured from the UV-vis-NIR absorption spectrum, and the observed absorption peak is assigned as a charge transfer from O 2p states to Pb 6p states.
DOI10.1039/c3nj00893b
收录类别SCI
WOS记录号WOS:000329886900037
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3842
专题中国科学院特殊环境功能材料与器件重点试验室
作者单位Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
YuHongwei,WuHongping,PanShilie,et al. Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain[J]. NEW JOURNAL OF CHEMISTRY,2014,38(1):285-291.
APA YuHongwei.,WuHongping.,PanShilie.,ZhangBingbing.,DongLingyun.,...&YangZhihua.(2014).Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain.NEW JOURNAL OF CHEMISTRY,38(1),285-291.
MLA YuHongwei,et al."Pb4Zn2B10O21: a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12](infinity) chain".NEW JOURNAL OF CHEMISTRY 38.1(2014):285-291.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Pb4Zn2B10O21 a congr(2084KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[YuHongwei]的文章
[WuHongping]的文章
[PanShilie]的文章
百度学术
百度学术中相似的文章
[YuHongwei]的文章
[WuHongping]的文章
[PanShilie]的文章
必应学术
必应学术中相似的文章
[YuHongwei]的文章
[WuHongping]的文章
[PanShilie]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Pb4Zn2B10O21 a congruently melting lead zinc borate with a novel [B10O24] anionic group and an interesting [Pb4O12]∞ chain.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。