Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains
Wang, Zheng; Zhang, Min; Pan, Shilie; Wang, Ying; Zhang, Hui; Chen, Zhaohui; Zhang, M.
2014
发表期刊Dalton Transactions
ISSN14779226
卷号43期号:7页码:2828-2834
摘要The first alkali metal and magnesium mixed borate fluoride, Li 0.8Mg2.1B2O5F, was prepared by the high-temperature solution method. It crystallizes in the monoclinic space group P21/n (no. 14) with lattice constants a = 3.0881(4) A˚, b = 13.6020(2) A˚, c = 9.6563(1) A˚, β = 91.744(9)°, Z = 4. In the structure, a special magnesium-oxygen-fluorine octahedral chain is found in borates for the first time. The octahedral chains are linked into a three-dimensional framework containing tunnels with 1 ∞[LiO4]7- chains and isolated B 2O5 groups filling in. The differences of octahedral chains in Li0.8Mg2.1B2O5F and magnesium inosilicate minerals are discussed. The TG-DSC curves, IR spectrum and UV-Vis-NIR diffuse reflectance spectrum were measured.
DOI10.1039/c3dt52592a
收录类别SCI
WOS记录号WOS:000330118000018
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被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3840
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Zhang, M.
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat, Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Wang, Zheng,Zhang, Min,Pan, Shilie,et al. Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains[J]. Dalton Transactions,2014,43(7):2828-2834.
APA Wang, Zheng.,Zhang, Min.,Pan, Shilie.,Wang, Ying.,Zhang, Hui.,...&Zhang, M..(2014).Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains.Dalton Transactions,43(7),2828-2834.
MLA Wang, Zheng,et al."Li0.8Mg2.1B2O5F: the first borate fluoride with magnesium-oxygen-fluorine octahedral chains".Dalton Transactions 43.7(2014):2828-2834.
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