Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O
Chen, Zhaohui; Pan, Shilie; Jing, Qun; Yang, Yun; Dong, Xiaoyu; Bian, Qiang; Han, Jian; Dong, Lingyun; Yang, Zhihua
2014
发表期刊ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
卷号640期号:1页码:140-146
摘要The organic-inorganic hybrid nonlinear optical (NLO) material NH4B(d-(+)-C4H4O5)(2)H2O (NBC) was synthesized in a borate-carboxylic acid system. Its structure was determined by single crystal X-ray diffraction. It crystallizes in the orthorhombic system, space group Pna2(1) (No. 33), with cell parameters a = 11.484(6) angstrom, b = 5.354(3) angstrom, c = 21.079(12) angstrom, V = 1296.0(12), Z = 4. It exhibits a three-dimensional pseudo tunnel structure consisting of fundamental building block [B(d-(+)-C4H4O5)(2)](-) anions. The small cavities are occupied by the H2O molecules and NH4+ cations, which stabilize the whole structure by O-HO and N-HO hydrogen bonds. The powder X-ray diffraction (PXRD) of the crystal was also recorded. Elemental analyses, FT-IR and FT-Raman spectra analyses, thermal analysis, and diffuse-reflectance spectra for the compound are also presented, as are band structures and density of states calculation. Nonlinear optical measurements indicate that the material has second harmonic generation (SHG) properties and is phase-matchable.
关键词Crystal Structure Crystal Growth Organic-inorganic Hybrid Nonlinear Optical Materials
DOI10.1002/zaac.201300202
收录类别SCI
WOS记录号WOS:000330595800024
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3839
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Xinjiang Univ, Phys & Chem Testing Ctr, Urumqi 830046, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Chen, Zhaohui,Pan, Shilie,Jing, Qun,et al. Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2014,640(1):140-146.
APA Chen, Zhaohui.,Pan, Shilie.,Jing, Qun.,Yang, Yun.,Dong, Xiaoyu.,...&Yang, Zhihua.(2014).Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,640(1),140-146.
MLA Chen, Zhaohui,et al."Preparation, Structure, and Second-order Nonlinear Optical Properties of a Borate-Carboxylic Acid Compound: NH4B[D-(+)-C4H4O5](2)center dot H2O".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 640.1(2014):140-146.
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