A new polymorph of Cd3B2O6: synthesis, crystal structure and phase transformation
Zhang, Xingwen; Yu, Hongwei; Wu, Hongping; Pan, Shilie; Jiao, Anqing; Zhang, Bingbing; Yang, Zhihua; Wu, HP
2014
发表期刊RSC Advances
ISSN2046-2069
卷号4期号:25页码:13195-13200
摘要A new polymorph of Cd3B2O6 (β-Cd 3B2O6) has been grown through spontaneous crystallization with the flux system. β-Cd3B2O 6 crystallizes in triclinic space group P1 and features a three-dimensional Cd-O network composed of CdOn (n = 5, 6) distorted polyhedra and isolated planar BO3 groups. The phase transformation of Cd3B2O6 has been studied by the structure analysis and powder X-ray diffraction. TG-DSC measurement reveals the melting behavior and phase transformation temperature. Furthermore, the IR spectrum was measured. The detailed structure comparison between Cd3B 2O6 and other cadmium-containing borates, such as CdB 4O7, CdB2O4 and Cd2B 2O5 was also carried out.
DOI10.1039/c4ra00671b
收录类别SCI
WOS记录号WOS:000332485000070
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3833
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Wu, HP
作者单位Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
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Zhang, Xingwen,Yu, Hongwei,Wu, Hongping,et al. A new polymorph of Cd3B2O6: synthesis, crystal structure and phase transformation[J]. RSC Advances,2014,4(25):13195-13200.
APA Zhang, Xingwen.,Yu, Hongwei.,Wu, Hongping.,Pan, Shilie.,Jiao, Anqing.,...&Wu, HP.(2014).A new polymorph of Cd3B2O6: synthesis, crystal structure and phase transformation.RSC Advances,4(25),13195-13200.
MLA Zhang, Xingwen,et al."A new polymorph of Cd3B2O6: synthesis, crystal structure and phase transformation".RSC Advances 4.25(2014):13195-13200.
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