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题名: A new polymorph of Cd3B2O6: synthesis, crystal structure and phase transformation
作者: Zhang, Xingwen; Yu, Hongwei; Wu, Hongping; Pan, Shilie; Jiao, Anqing; Zhang, Bingbing; Yang, Zhihua
通讯作者: Wu, HP
刊名: RSC Advances
发表日期: 2014
DOI: 10.1039/c4ra00671b
卷: 4, 期:25, 页:13195-13200
收录类别: SCI
摘要: A new polymorph of Cd3B2O6 (β-Cd 3B2O6) has been grown through spontaneous crystallization with the flux system. β-Cd3B2O 6 crystallizes in triclinic space group P1 and features a three-dimensional Cd-O network composed of CdOn (n = 5, 6) distorted polyhedra and isolated planar BO3 groups. The phase transformation of Cd3B2O6 has been studied by the structure analysis and powder X-ray diffraction. TG-DSC measurement reveals the melting behavior and phase transformation temperature. Furthermore, the IR spectrum was measured. The detailed structure comparison between Cd3B 2O6 and other cadmium-containing borates, such as CdB 4O7, CdB2O4 and Cd2B 2O5 was also carried out.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3833
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China

Recommended Citation:
Zhang, Xingwen,Yu, Hongwei,Wu, Hongping,et al. A new polymorph of Cd3B2O6: synthesis, crystal structure and phase transformation[J]. RSC Advances,2014,4(25):13195-13200.
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文件名: A new polymorph of Cd3B2O6 synthesis, crystal structure and phase transformation.pdf
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