New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group
Wu, Hongping; Yu, Hongwei; Pan, Shilie; Jiao, Anqing; Han, Jian; Wu, Kui; Han, Shujuan; Li, Hongyi; Wu, HP
2014
发表期刊Dalton Transactions
ISSN14779226
卷号43期号:12页码:4886-4891
摘要Compounds with isolated anionic groups often exhibit special linear and nonlinear optical properties and possess potential applications such as birefringence, second harmonic generation and stimulated Raman scattering crystals. In this paper, two new alkali and alkaline earth mixed-metal borates, Li3KB4O8 and LiNa2Sr 8B12O24F6Cl, with isolated (B 12O24)12- anionic groups have been successfully synthesized by spontaneous crystallization. Their structures were determined by single crystal X-ray diffraction and they both crystallize in the same space group, R3. More interestingly, further structure comparison shows that the discovered anhydrous borates with the (B12O24) 12- groups also crystallize in the same space group R3, which is related with the local symmetry of the (B12O24) 12- groups. These structural features suggest that the crystal structures of the family of compounds depend more on their anionic groups. In addition, the property characterizations of the two new borates were investigated by TG-DSC, IR and UV-vis-NIR diffuse reflectance.
DOI10.1039/c3dt53115e
收录类别SCI
WOS记录号WOS:000332390500033
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3832
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Wu, HP
作者单位Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
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Wu, Hongping,Yu, Hongwei,Pan, Shilie,et al. New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group[J]. Dalton Transactions,2014,43(12):4886-4891.
APA Wu, Hongping.,Yu, Hongwei.,Pan, Shilie.,Jiao, Anqing.,Han, Jian.,...&Wu, HP.(2014).New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group.Dalton Transactions,43(12),4886-4891.
MLA Wu, Hongping,et al."New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group".Dalton Transactions 43.12(2014):4886-4891.
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