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题名: New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group
作者: Wu, Hongping; Yu, Hongwei; Pan, Shilie; Jiao, Anqing; Han, Jian; Wu, Kui; Han, Shujuan; Li, Hongyi
通讯作者: Wu, HP
刊名: Dalton Transactions
发表日期: 2014
DOI: 10.1039/c3dt53115e
卷: 43, 期:12, 页:4886-4891
收录类别: SCI
摘要: Compounds with isolated anionic groups often exhibit special linear and nonlinear optical properties and possess potential applications such as birefringence, second harmonic generation and stimulated Raman scattering crystals. In this paper, two new alkali and alkaline earth mixed-metal borates, Li3KB4O8 and LiNa2Sr 8B12O24F6Cl, with isolated (B 12O24)12- anionic groups have been successfully synthesized by spontaneous crystallization. Their structures were determined by single crystal X-ray diffraction and they both crystallize in the same space group, R3. More interestingly, further structure comparison shows that the discovered anhydrous borates with the (B12O24) 12- groups also crystallize in the same space group R3, which is related with the local symmetry of the (B12O24) 12- groups. These structural features suggest that the crystal structures of the family of compounds depend more on their anionic groups. In addition, the property characterizations of the two new borates were investigated by TG-DSC, IR and UV-vis-NIR diffuse reflectance.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3832
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China

Recommended Citation:
Wu, Hongping,Yu, Hongwei,Pan, Shilie,et al. New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group[J]. Dalton Transactions,2014,43(12):4886-4891.
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文件名: New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group .pdf
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