New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group
Wu, Hongping; Yu, Hongwei; Pan, Shilie; Jiao, Anqing; Han, Jian; Wu, Kui; Han, Shujuan; Li, Hongyi; Wu, HP
2014
Source PublicationDalton Transactions
ISSN14779226
Volume43Issue:12Pages:4886-4891
AbstractCompounds with isolated anionic groups often exhibit special linear and nonlinear optical properties and possess potential applications such as birefringence, second harmonic generation and stimulated Raman scattering crystals. In this paper, two new alkali and alkaline earth mixed-metal borates, Li3KB4O8 and LiNa2Sr 8B12O24F6Cl, with isolated (B 12O24)12- anionic groups have been successfully synthesized by spontaneous crystallization. Their structures were determined by single crystal X-ray diffraction and they both crystallize in the same space group, R3. More interestingly, further structure comparison shows that the discovered anhydrous borates with the (B12O24) 12- groups also crystallize in the same space group R3, which is related with the local symmetry of the (B12O24) 12- groups. These structural features suggest that the crystal structures of the family of compounds depend more on their anionic groups. In addition, the property characterizations of the two new borates were investigated by TG-DSC, IR and UV-vis-NIR diffuse reflectance.
DOI10.1039/c3dt53115e
Indexed BySCI
WOS IDWOS:000332390500033
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3832
Collection中国科学院特殊环境功能材料与器件重点试验室
Corresponding AuthorWu, HP
AffiliationKey Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
Recommended Citation
GB/T 7714
Wu, Hongping,Yu, Hongwei,Pan, Shilie,et al. New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group[J]. Dalton Transactions,2014,43(12):4886-4891.
APA Wu, Hongping.,Yu, Hongwei.,Pan, Shilie.,Jiao, Anqing.,Han, Jian.,...&Wu, HP.(2014).New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group.Dalton Transactions,43(12),4886-4891.
MLA Wu, Hongping,et al."New type of complex alkali and alkaline earth metal borates with isolated (B12O24)(12-) anionic group".Dalton Transactions 43.12(2014):4886-4891.
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