Ba-4(BO3)(3)(SiO4)center dot Ba3X(X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials
Lin, Xiaoxia; Zhang, Fangfang; Pan, Shilie; Yu, Hongwei; Zhang, Fangyuan; Dong, Xiaoyu; Han, Shujuan; Dong, Lingyun; Bai, Chunyan; Wang, Zheng
2014
Source PublicationJournal of Materials Chemistry C
ISSN2050-7526
Volume2Issue:21Pages:4257-4264
Abstract

Based on the combination of two different anionic groups (SiO4 and BO3) and the utility of a XBa6 (X = Cl, Br) polar template, two new salt-inclusion compounds, Ba4(BO3) 3(SiO4)·Ba3X (X = Cl, Br) have been successfully synthesized by the high-temperature solution method for the first time. They are isostructural and their structures feature the ∞3[Ba4(BO3) 3(SiO4)] framework with 1D channels along the c axis, in which resided the polar ∞1[Ba3X] chains. It is worth noting that they are the first alkaline-earth metal borosilicate halides to be used as nonlinear optical (NLO) materials. The second harmonic generation (SHG) measurements show that they have SHG responses similar to that of KH2PO4 (KDP) and are type-I phase-matchable. In addition, they melt congruently and exhibit a wide transparent region with the UV cut-off edge below 190 nm. These properties make Ba4(BO 3)3(SiO4)·Ba3X potential deep UV NLO materials.

DOI10.1039/c4tc00079j
Indexed BySCI
WOS IDWOS:000336038400021
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3826
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, Fangfang
Affiliation1.Xinjiang Tech Inst Phys & Chem CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
Recommended Citation
GB/T 7714
Lin, Xiaoxia,Zhang, Fangfang,Pan, Shilie,et al. Ba-4(BO3)(3)(SiO4)center dot Ba3X(X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials[J]. Journal of Materials Chemistry C,2014,2(21):4257-4264.
APA Lin, Xiaoxia.,Zhang, Fangfang.,Pan, Shilie.,Yu, Hongwei.,Zhang, Fangyuan.,...&Wang, Zheng.(2014).Ba-4(BO3)(3)(SiO4)center dot Ba3X(X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials.Journal of Materials Chemistry C,2(21),4257-4264.
MLA Lin, Xiaoxia,et al."Ba-4(BO3)(3)(SiO4)center dot Ba3X(X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials".Journal of Materials Chemistry C 2.21(2014):4257-4264.
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