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题名: KI Dispersed onto MCM-41 as Catalytic Sites for the Cycloaddition of Cyclic Carbonates from Epoxides and CO2
作者: Zhou, Liang; Cai, Guoxing; Zhang, Letao; Luo, Yanping; He, Zhenhong; Eli, Wumanjiang
关键词: catalytic performance ; carbon dioxide ; cyclic carbonates ; epoxides ; KI ; MCM-41 ; structure characterization
刊名: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
发表日期: 2014
DOI: 10.1080/15533174.2013.818025
卷: 44, 期:10, 页:1545-1550
收录类别: SCI
摘要: Supported KI/MCM-41 catalysts were prepared by the incipient wetness impregnation method and characterized by XRD, SEM, TEM, and N-2 adsorption-desorption techniques. It was confirmed that KI on MCM-41 are small in size and even in dispersion. KI/MCM-41 catalyst with a 35% loading of KI has given excellent catalytic activity and stability in the synthesis of various carbonates. The catalyst was easily recovered and could be reused at four times without much loss of activity. In addition, the reaction mechanism was discussed on the basis of the experimental results.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3820
Appears in Collections:新疆维吾尔自治区精细化工工程技术研究中心_期刊论文

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作者单位: Chinese Acad Sci, Fine Chem Ind Engn Technol Ctr, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing, Peoples R China

Recommended Citation:
Zhou, Liang,Cai, Guoxing,Zhang, Letao,et al. KI Dispersed onto MCM-41 as Catalytic Sites for the Cycloaddition of Cyclic Carbonates from Epoxides and CO2[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY,2014,44(10):1545-1550.
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文件名: KI Dispersed onto MCM-41 as Catalytic Sites for the Cycloaddition of Cyclic Carbonates from Epoxides and CO2.pdf
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