Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)
Wang, Zheng; Zhang, Min; Pan, Shilie; Yang, Zhihua; Zhang, Hui; Zhang, Bingbing; Wang, Ying; Kang, Jing; Lin, Xiaoxia
2014
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume38Issue:7Pages:3035-3041
Abstract

The structures of three borates with isolated BO3 groups, RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4), are determined from single crystal diffraction data for the first time. The introduction of small cations (Mg2+ and Zn2+) with strong bonding can prevent the formation of the B-O network effectively, and is beneficial to obtain the isolated BO3 groups. Moreover, the cationic skeletons composed of small cations significantly affect the arrangement of isolated BO3 groups. Thermal analysis, infrared and UV-Vis-NIR diffuse reflectance spectroscopy, and electronic band structure calculations were performed for the reported materials.

DOI10.1039/c4nj00363b
Indexed BySCI
WOS IDWOS:000338117900044
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3817
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, Min
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Zheng,Zhang, Min,Pan, Shilie,et al. Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)[J]. NEW JOURNAL OF CHEMISTRY,2014,38(7):3035-3041.
APA Wang, Zheng.,Zhang, Min.,Pan, Shilie.,Yang, Zhihua.,Zhang, Hui.,...&Lin, Xiaoxia.(2014).Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4).NEW JOURNAL OF CHEMISTRY,38(7),3035-3041.
MLA Wang, Zheng,et al."Exploring the influence of cationic skeletons on the arrangement of isolated BO3 groups based on RbMgBO3, CsZn4(BO3)(3) and Cs4Mg4(BO3)(4)".NEW JOURNAL OF CHEMISTRY 38.7(2014):3035-3041.
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