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Efficient Synthesis of alpha-Quaternary alpha-Hydroxy-beta-amino Esters via Silyl Glyoxylate-Mediated Three-Component Reactions
Jiang, Jiu-Long; Yao, Ming; Lu, Chong-Dao; Lu, CD
2014
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume16Issue:1Pages:318-321
AbstractAn efficient method has been developed for the enantioselective synthesis of fully protected alpha-quaternary alpha-hydroxy-beta-amino esters via the coupling of three components: aryl Grignard reagents (or methyllithium), silyl glyoxylate, and N-tert-butanesulfinyl imines. This protocol enables successive formation of two C-C bonds and two adjacent chiral carbons with high stereocontrol in a one-pot operation.
DOI10.1021/ol403388w
Indexed BySCI
WOS IDWOS:000329472800082
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3812
Collection资源化学研究室
Corresponding AuthorLu, CD
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Jiang, Jiu-Long,Yao, Ming,Lu, Chong-Dao,et al. Efficient Synthesis of alpha-Quaternary alpha-Hydroxy-beta-amino Esters via Silyl Glyoxylate-Mediated Three-Component Reactions[J]. ORGANIC LETTERS,2014,16(1):318-321.
APA Jiang, Jiu-Long,Yao, Ming,Lu, Chong-Dao,&Lu, CD.(2014).Efficient Synthesis of alpha-Quaternary alpha-Hydroxy-beta-amino Esters via Silyl Glyoxylate-Mediated Three-Component Reactions.ORGANIC LETTERS,16(1),318-321.
MLA Jiang, Jiu-Long,et al."Efficient Synthesis of alpha-Quaternary alpha-Hydroxy-beta-amino Esters via Silyl Glyoxylate-Mediated Three-Component Reactions".ORGANIC LETTERS 16.1(2014):318-321.
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