Synthesis, crystal structure and optical properties of Ba5V3O12F
Kang, Jing; Yang, Yun; Pan, Shilie; Yu, Hongwei; Zhou, Zhongxiang
2014
Source PublicationJournal of Molecular Structure
ISSN0022-2860
Volume1056Issue:1Pages:79-83
Abstract

Colorless and transparent Ba5V3O12F crystal has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction and physical properties analyses. Ba 5V3O12F crystallizes in the hexagonal system with space group P63/m. The structure of apatite-like compound Ba5V3O12F can be described on the basis of a "framework" made of Ba(2)O6 polyhedra and VO4 tetrahedra, which form [0 0 1]-channels filled with Ba(1) cations and F anions. The VO4 groups presented in the sample are identified by Fourier transform infrared spectrum. UV-Vis-NIR diffuse reflectance spectrum of Ba 5V3O12F shows that it has a wide transmittance range from 322 to 2600 nm.

KeywordBa5v3o12f Apatite Vanadium-oxide-based Compounds Synthesis Crystal Structure
DOI10.1016/j.molstruc.2013.10.009
Indexed BySCI
WOS IDWOS:000330147900011
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3811
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Affiliation1.Key Lab Funct Mat & Devices Special Environm CAS, Xian, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi, Peoples R China
3.Xinjiang Tech Inst Phys & Chem CAS, Urumqi 830011, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Kang, Jing,Yang, Yun,Pan, Shilie,et al. Synthesis, crystal structure and optical properties of Ba5V3O12F[J]. Journal of Molecular Structure,2014,1056(1):79-83.
APA Kang, Jing,Yang, Yun,Pan, Shilie,Yu, Hongwei,&Zhou, Zhongxiang.(2014).Synthesis, crystal structure and optical properties of Ba5V3O12F.Journal of Molecular Structure,1056(1),79-83.
MLA Kang, Jing,et al."Synthesis, crystal structure and optical properties of Ba5V3O12F".Journal of Molecular Structure 1056.1(2014):79-83.
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