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题名: Synthesis, crystal structure and optical properties of Ba5V3O12F
作者: Kang, Jing; Yang, Yun; Pan, Shilie; Yu, Hongwei; Zhou, Zhongxiang
关键词: Ba5V3O12F ; Apatite ; Vanadium-oxide-based compounds ; Synthesis ; Crystal structure
刊名: Journal of Molecular Structure
发表日期: 2014
DOI: 10.1016/j.molstruc.2013.10.009
卷: 1056, 期:1, 页:79-83
收录类别: SCI
摘要: Colorless and transparent Ba5V3O12F crystal has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction and physical properties analyses. Ba 5V3O12F crystallizes in the hexagonal system with space group P63/m. The structure of apatite-like compound Ba5V3O12F can be described on the basis of a "framework" made of Ba(2)O6 polyhedra and VO4 tetrahedra, which form [0 0 1]-channels filled with Ba(1) cations and F anions. The VO4 groups presented in the sample are identified by Fourier transform infrared spectrum. UV-Vis-NIR diffuse reflectance spectrum of Ba 5V3O12F shows that it has a wide transmittance range from 322 to 2600 nm.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3811
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Key Lab Funct Mat & Devices Special Environm CAS, Xian, Peoples R China;Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi, Peoples R China; Xinjiang Tech Inst Phys & Chem CAS, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Kang, Jing,Yang, Yun,Pan, Shilie,et al. Synthesis, crystal structure and optical properties of Ba5V3O12F[J]. Journal of Molecular Structure,2014,1056(1):79-83.
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文件名: Synthesis, crystal structure and optical properties of Ba5V3O12F .pdf
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