Cs3Zn6B9O21: A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response
Yu, Hongwei; Wu, Hongping; Pan, Shilie; Yang, Zhihua; Hou, Xueling; Su, Xin; Jing, Qun; Poeppelmeier, Kenneth R.; Rondinelli, James M.
2014
Source PublicationJournal of the American Chemical Society
ISSN0002-7863
Volume136Issue:4Pages:1264-1267
Abstract

Nonlinear optical (NLO) crystals are essential materials for generation of coherent UV light in solid state lasers. KBBF is the only material that can achieve coherent light below 200 nm by direct second harmonic generation (SHG). However, its strong layer habits and the high toxicity of the beryllium oxide powders required for synthesis limit its application. By substituting Be with Zn and connecting adjacent [Zn2BO3O2] ∞ layers by B3O6 groups, a new UV nonlinear optical material, Cs3Zn6B9O 21, was synthesized. It overcomes the processing limitations of KBBF and exhibits the largest SHG response in the KBBF family.

DOI10.1021/ja4117389
Indexed BySCI
WOS IDWOS:000330598600028
Citation statistics
Cited Times:167[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3809
Collection中国科学院特殊环境功能材料与器件重点试验室
资源化学研究室
材料物理与化学研究室
Corresponding AuthorPan, Shilie
Affiliation1.Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China
2.Xinjiang Tech Inst Phys & Chem CAS, Urumqi 830011, Peoples R China
3.Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
6.Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
Recommended Citation
GB/T 7714
Yu, Hongwei,Wu, Hongping,Pan, Shilie,et al. Cs3Zn6B9O21: A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response[J]. Journal of the American Chemical Society,2014,136(4):1264-1267.
APA Yu, Hongwei.,Wu, Hongping.,Pan, Shilie.,Yang, Zhihua.,Hou, Xueling.,...&Rondinelli, James M..(2014).Cs3Zn6B9O21: A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response.Journal of the American Chemical Society,136(4),1264-1267.
MLA Yu, Hongwei,et al."Cs3Zn6B9O21: A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response".Journal of the American Chemical Society 136.4(2014):1264-1267.
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