Synthesis, structure, and characterization of a new rubidium cadmium borate: RbCdB3O6
Jiao, Anqing; Wu, Hongping; Pan, Shilie; Yu, Hongwei; Yang, Zhihua; Lei, Chen; Wu, H.(wuhp@ms.xjb.ac.cn)
2014
发表期刊Journal of Alloys and Compounds
ISSN9258388
卷号588期号:3页码:514-518
摘要A new ternary borate, RbCdB3O6 has been synthesized by solid-state reaction and its structure was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group C2/c, and in its crystal structure, RbO10 polyhedra and B3O6 rings comprise a three dimensional (3D) framework containing tunnels viewing along [1 0 1] direction in which Cd atoms are located to balance the charge. A comparison of the structures of RbCdB3O6, α-BaB 2O4 and β-BaB2O4 is presented. The IR, UV-Vis-IR absorption spectra and the thermal properties of RbCdB 3O6 have also been reported. The electronic structure and birefringence have been calculated by the first-principle method based on the density-functional theory.
关键词Rbcdb3o6 X-ray Diffraction Synthesis Crystal Structure Electronic Structure
DOI10.1016/j.jallcom.2013.11.037
收录类别SCI
WOS记录号WOS:000330179200084
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3800
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Wu, H.(wuhp@ms.xjb.ac.cn)
作者单位Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
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Jiao, Anqing,Wu, Hongping,Pan, Shilie,et al. Synthesis, structure, and characterization of a new rubidium cadmium borate: RbCdB3O6[J]. Journal of Alloys and Compounds,2014,588(3):514-518.
APA Jiao, Anqing.,Wu, Hongping.,Pan, Shilie.,Yu, Hongwei.,Yang, Zhihua.,...&Wu, H..(2014).Synthesis, structure, and characterization of a new rubidium cadmium borate: RbCdB3O6.Journal of Alloys and Compounds,588(3),514-518.
MLA Jiao, Anqing,et al."Synthesis, structure, and characterization of a new rubidium cadmium borate: RbCdB3O6".Journal of Alloys and Compounds 588.3(2014):514-518.
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