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题名: Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response
作者: Li, Hongyi; Wu, Hongping; Su, Xin; Yu, Hongwei; Pan, Shilie; Yang, Zhihua; Lu, Yi; Han, Jian; Poeppelmeier, Kenneth R.
通讯作者: Pan, SL
刊名: Journal of Materials Chemistry C
发表日期: 2014
DOI: 10.1039/c3tc32002b
卷: 2, 期:9, 页:1704-1710
收录类别: SCI
摘要: The introduction of Pb2+ cations with the lone pair effect and the largest electronegativity of F- anions successfully results in a new non-centrosymmetric lead borate fluoride, Pb3B6O 11F2, which possesses a large SHG response about four times that of KH2PO4 (KDP) and is type-I phase matchable. The structure is built from a 3-dimensional B-O network composed of hexaborate B6O14 groups and novel [FPb3]∞ layers. First-principles electronic structure calculations show that the calculated birefringence of Pb3B6O11F 2 is about 0.07 in the visible region. Based on the measurement of the UV-Vis-NIR diffuse-reflectance spectrum, it exhibits a wide transparency range with a short UV cut-off edge at about 240 nm. All these properties indicate that Pb3B6O11F2 is a promising nonlinear optical crystal in the UV region.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3799
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China

Recommended Citation:
Li, Hongyi,Wu, Hongping,Su, Xin,et al. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response[J]. Journal of Materials Chemistry C,2014,2(9):1704-1710.
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文件名: Pb3B6O11F2 the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response .pdf
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