Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response
Li, Hongyi; Wu, Hongping; Su, Xin; Yu, Hongwei; Pan, Shilie; Yang, Zhihua; Lu, Yi; Han, Jian; Poeppelmeier, Kenneth R.
2014
Source PublicationJournal of Materials Chemistry C
ISSN2050-7526
Volume2Issue:9Pages:1704-1710
Abstract

The introduction of Pb2+ cations with the lone pair effect and the largest electronegativity of F- anions successfully results in a new non-centrosymmetric lead borate fluoride, Pb3B6O 11F2, which possesses a large SHG response about four times that of KH2PO4 (KDP) and is type-I phase matchable. The structure is built from a 3-dimensional B-O network composed of hexaborate B6O14 groups and novel [FPb3]∞ layers. First-principles electronic structure calculations show that the calculated birefringence of Pb3B6O11F 2 is about 0.07 in the visible region. Based on the measurement of the UV-Vis-NIR diffuse-reflectance spectrum, it exhibits a wide transparency range with a short UV cut-off edge at about 240 nm. All these properties indicate that Pb3B6O11F2 is a promising nonlinear optical crystal in the UV region.

DOI10.1039/c3tc32002b
Indexed BySCI
WOS IDWOS:000331917600018
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3799
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, Shilie
Affiliation1.Xinjiang Tech Inst Phys & Chem CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xinjiang Prod Qual Supervis & Inspect Inst Techno, Urumqi 830011, Peoples R China
4.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
Recommended Citation
GB/T 7714
Li, Hongyi,Wu, Hongping,Su, Xin,et al. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response[J]. Journal of Materials Chemistry C,2014,2(9):1704-1710.
APA Li, Hongyi.,Wu, Hongping.,Su, Xin.,Yu, Hongwei.,Pan, Shilie.,...&Poeppelmeier, Kenneth R..(2014).Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response.Journal of Materials Chemistry C,2(9),1704-1710.
MLA Li, Hongyi,et al."Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response".Journal of Materials Chemistry C 2.9(2014):1704-1710.
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