Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response
Li, Hongyi; Wu, Hongping; Su, Xin; Yu, Hongwei; Pan, Shilie; Yang, Zhihua; Lu, Yi; Han, Jian; Poeppelmeier, Kenneth R.; Pan, SL
2014
发表期刊Journal of Materials Chemistry C
ISSN20507534
卷号2期号:9页码:1704-1710
摘要The introduction of Pb2+ cations with the lone pair effect and the largest electronegativity of F- anions successfully results in a new non-centrosymmetric lead borate fluoride, Pb3B6O 11F2, which possesses a large SHG response about four times that of KH2PO4 (KDP) and is type-I phase matchable. The structure is built from a 3-dimensional B-O network composed of hexaborate B6O14 groups and novel [FPb3]∞ layers. First-principles electronic structure calculations show that the calculated birefringence of Pb3B6O11F 2 is about 0.07 in the visible region. Based on the measurement of the UV-Vis-NIR diffuse-reflectance spectrum, it exhibits a wide transparency range with a short UV cut-off edge at about 240 nm. All these properties indicate that Pb3B6O11F2 is a promising nonlinear optical crystal in the UV region.
DOI10.1039/c3tc32002b
收录类别SCI
WOS记录号WOS:000331917600018
引用统计
被引频次:31[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3799
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Pan, SL
作者单位Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics and Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
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Li, Hongyi,Wu, Hongping,Su, Xin,et al. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response[J]. Journal of Materials Chemistry C,2014,2(9):1704-1710.
APA Li, Hongyi.,Wu, Hongping.,Su, Xin.,Yu, Hongwei.,Pan, Shilie.,...&Pan, SL.(2014).Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response.Journal of Materials Chemistry C,2(9),1704-1710.
MLA Li, Hongyi,et al."Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response".Journal of Materials Chemistry C 2.9(2014):1704-1710.
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