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XJIPC OpenIR  > 省部共建新疆特有药用资源利用重点实验室  > 期刊论文
题名:
MgCl2-Catalyzed alpha-Amination of alpha-Alkyl-beta-ketoesters via Oxidative N-Acyl-nitroso Aldol Reaction with Hydroxamic Acids
作者: Liang, Ming-Qiang; Lu, Chong-Dao
通讯作者: Lu, CD
关键词: amination ; -alkyl--ketoesters ; catalysis ; magnesium chloride ; acylnitroso
刊名: SYNLETT
发表日期: 2014
DOI: 10.1055/s-0033-1340954
卷: 25, 期:7, 页:991-994
收录类别: SCI
英文摘要:

A practical method for alpha-amination of alpha-alkyl-beta-ketoesters using hydroxamic acids is described. In this protocol, an oxidative N-acylnitroso aldol reaction is catalyzed by magnesium chloride in the presence of the oxidant tert-butyl hydroperoxide.

WOS记录号: WOS:000334166100019
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3788
Appears in Collections:新疆维吾尔自治区植物资源化学重点实验室 _期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Liang, Ming-Qiang,Lu, Chong-Dao. MgCl2-Catalyzed alpha-Amination of alpha-Alkyl-beta-ketoesters via Oxidative N-Acyl-nitroso Aldol Reaction with Hydroxamic Acids[J]. SYNLETT,2014-01-01,25(7):991-994.
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