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Transformation of polycyclic aromatic hydrocarbons (PAHs) on Fe(III)-modified clay minerals: Role of molecular chemistry and clay surface properties
Jia, Hanzhong; Zhao, Jincai; Li, Li; Li, Xiyou; Wang, Chuanyi; Wang, CY
2014
发表期刊Applied Catalysis B: Environmental
ISSN9263373
卷号154-155期号:7页码:238-245
摘要Clay-driven transformation of polycyclic aromatic hydrocarbons (PAHs) is critically influenced by their molecular structure and clay surface properties. In the present study, several PAHs were selected as model molecules to investigate their potential transformation on Fe(III)-saturated clay minerals under various mineralogical and environmental conditions. Results suggest that the reactivity of PAHs is highly correlated with their ionization potential (IP) values. PAHs with IP lower than a threshold between 7.5 and 7.6 prefer undergoing a one-electron transfer reaction. Otherwise, Fe(III)-smectite is unable to degrade PAHs with IP above it. The electron-transfer process leads to the reduction of Fe(III) to Fe(II) and formation of organic radical cations, which are more stable in clay interlayers than at other clay sites. Subsequent reactions of radical cations with oxygenic species (such as H2O) result in formation of oxygenated products. The surface chemical properties, i.e., the hydration of cations, fraction of Fe(III), layer charge location, and type of ligands, strongly affect the interaction between PAHs and Fe(III), thus modulate the reactivity of surface Fe(III)-species on the clay minerals. This study provides the first direct evidence for clay-catalyzed transformation of PAHs supporting the plausibility of their in situ degradation in soils, and demonstrates that abiotic reactions with surface-bound Fe(III) may affect or even dominate the long-term behavior of PAHs in soils, particularly in the presence of swelling clay minerals.
关键词Clay Minerals Polycyclic Aromatic Hydrocarbons (Pahs) Ionization Potential Electron Transfer Transformation
DOI10.1016/j.apcatb.2014.02.022
收录类别SCI
WOS记录号WOS:000335098800028
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3769
专题环境科学与技术研究室
通讯作者Wang, CY
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Xinjiang, Peoples R China;Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Jia, Hanzhong,Zhao, Jincai,Li, Li,et al. Transformation of polycyclic aromatic hydrocarbons (PAHs) on Fe(III)-modified clay minerals: Role of molecular chemistry and clay surface properties[J]. Applied Catalysis B: Environmental,2014,154-155(7):238-245.
APA Jia, Hanzhong,Zhao, Jincai,Li, Li,Li, Xiyou,Wang, Chuanyi,&Wang, CY.(2014).Transformation of polycyclic aromatic hydrocarbons (PAHs) on Fe(III)-modified clay minerals: Role of molecular chemistry and clay surface properties.Applied Catalysis B: Environmental,154-155(7),238-245.
MLA Jia, Hanzhong,et al."Transformation of polycyclic aromatic hydrocarbons (PAHs) on Fe(III)-modified clay minerals: Role of molecular chemistry and clay surface properties".Applied Catalysis B: Environmental 154-155.7(2014):238-245.
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