Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals
Bai, Chunyan; Lei, Chen; Pan, Shilie; Wang, Ying; Yang, Zhihua; Han, Shujuan; Yu, Hongwei; Yang, Yun; Zhang, Fangyuan; Pan, SL
2014
发表期刊Solid State Sciences
ISSN12932558
卷号33期号:7页码:32-37
摘要Two new compounds, Rb3Na(MoO4)2 and Rb3Na(WO4)2, have been synthesized by conventional solid-state reaction. Single-crystal X-ray diffraction analysis revealed that they crystallize in the same space group P3¯m1 (No. 164) with the trigonal unit cell sizes of a = 6.138(2) A˚, c = 7.844(3) A˚ for the Mo compound and a = 6.161(4) A˚, c = 7.847(6) A˚ for the W compound. Both structures contain an infinite three-dimensional (3D) matrix that is built from isolated MO4 (M = Mo, W) tetrahedra, Rb(1)O 12, Rb(2)O10 polyhedra and NaO6 octahedra. In addition, the infrared spectroscopy spectrum (IR) and bond valence sums (BVS) calculations are used to verify the validity of the structures. The differential scanning calorimetry (DSC) and powder X-ray diffraction (XRD) results prove that both of them are congruently melting compounds. And the first-principle theoretical studies are also carried out to aid the understanding of their electronic structures.
关键词Rb3na(Moo4)(2) Rb3na(Wo4)(2) Crystal Structure X-ray Diffraction
DOI10.1016/j.solidstatesciences.2014.04.011
收录类别SCI
WOS记录号WOS:000338623500006
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3765
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Pan, SL
作者单位Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Bai, Chunyan,Lei, Chen,Pan, Shilie,et al. Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals[J]. Solid State Sciences,2014,33(7):32-37.
APA Bai, Chunyan.,Lei, Chen.,Pan, Shilie.,Wang, Ying.,Yang, Zhihua.,...&Pan, SL.(2014).Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals.Solid State Sciences,33(7),32-37.
MLA Bai, Chunyan,et al."Syntheses, structures and characterizations of Rb3Na(MO4)(2) (M = Mo, W) crystals".Solid State Sciences 33.7(2014):32-37.
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