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Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5
Guo, Xinfeng; Wu, Hongping; Pan, Shilie; Yang, Zhihua; Yu, Hongwei; Zhang, Bingbing; Han, Jian; Zhang, Fangyuan
2014
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
Volume640Issue:8-9Pages:1805-1809
AbstractA congruent melting compound MgSrB2O5 was synthesized by high temperature solution method from the MgO-SrO-B2O3 system, and the structure was determined by single-crystal X-ray diffraction methods. The compound crystallizes in the monoclinic system, with space group P2(1)/c. The crystal structure is composed of isolated B2O5 units and MgO6 octahedra that are connected to form two-dimensional [Mg2B4O10] layers stacking along the c axis. The layers are bridged by the Sr2+ cations to form a three-dimensional framework. The IR spectrum and the thermal properties of MgSrB2O5 were also reported. Additionally, detailed structure comparisons between MgSrB2O5 and other borates, such as Mg2B2O5, Sr2B2O5 and SrCdB2O5 are carried out and the first-principle theoretical studies are performed to aid the understanding of electronic structures and linear optical properties.
KeywordBorates Congruent Melting Compound Magnesium Mgsrb2o5 Diborate
DOI10.1002/zaac.201400043
Indexed BySCI
WOS IDWOS:000339561500043
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Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3764
Collection支撑部门
材料物理与化学研究室
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Guo, Xinfeng,Wu, Hongping,Pan, Shilie,et al. Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2014,640(8-9):1805-1809.
APA Guo, Xinfeng.,Wu, Hongping.,Pan, Shilie.,Yang, Zhihua.,Yu, Hongwei.,...&Zhang, Fangyuan.(2014).Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,640(8-9),1805-1809.
MLA Guo, Xinfeng,et al."Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 640.8-9(2014):1805-1809.
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