The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)
Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping; Yang, Zhihua; Wang, Xian; Han, J
2014
发表期刊EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
期号22页码:3467-3473
摘要Compounds containing both B-O and P-O groups are of wide interest and have been classified into borophosphates and borate-phosphates by R. Kniep et al. In addition to the B/P ratio, analysis results show that regulating the [M/(B+P)] ratio is also an effective strategy to synthesize new borate-phosphates. The first lithium lead borate-phosphate, LiPb4(BO3)(PO4)(2), was synthesized by regulating this ratio. This compound crystallizes in the orthorhombic space group Pbca (No. 61). It possesses a 3D structure with a corrugated 2D layer of [B2Pb8O18] that is further connected by a [LiP2O8] chain; both BO3 and PO4 were isolated. First-principle theoretical studies were performed to aid the understanding of the electronic structures and the linear optical properties. In addition, thermal analysis, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy were performed on the reported material.
关键词Synthesis Design Chain Structures Borates Phosphates Lead
DOI10.1002/ejic.201402389
收录类别SCI
WOS记录号WOS:000340416000004
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文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3755
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Han, J
作者单位Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Huang, Shengshi,Yu, Hongwei,Han, Jian,et al. The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2014(22):3467-3473.
APA Huang, Shengshi.,Yu, Hongwei.,Han, Jian.,Pan, Shilie.,Jing, Qun.,...&Han, J.(2014).The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(22),3467-3473.
MLA Huang, Shengshi,et al."The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .22(2014):3467-3473.
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