The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)
Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping; Yang, Zhihua; Wang, Xian
2014
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue22Pages:3467-3473
Abstract

Compounds containing both B-O and P-O groups are of wide interest and have been classified into borophosphates and borate-phosphates by R. Kniep et al. In addition to the B/P ratio, analysis results show that regulating the [M/(B+P)] ratio is also an effective strategy to synthesize new borate-phosphates. The first lithium lead borate-phosphate, LiPb4(BO3)(PO4)(2), was synthesized by regulating this ratio. This compound crystallizes in the orthorhombic space group Pbca (No. 61). It possesses a 3D structure with a corrugated 2D layer of [B2Pb8O18] that is further connected by a [LiP2O8] chain; both BO3 and PO4 were isolated. First-principle theoretical studies were performed to aid the understanding of the electronic structures and the linear optical properties. In addition, thermal analysis, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy were performed on the reported material.

KeywordSynthesis Design Chain Structures Borates Phosphates Lead
DOI10.1002/ejic.201402389
Indexed BySCI
WOS IDWOS:000340416000004
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3755
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorHan, Jian
AffiliationXinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Huang, Shengshi,Yu, Hongwei,Han, Jian,et al. The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2014(22):3467-3473.
APA Huang, Shengshi.,Yu, Hongwei.,Han, Jian.,Pan, Shilie.,Jing, Qun.,...&Wang, Xian.(2014).The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(22),3467-3473.
MLA Huang, Shengshi,et al."The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .22(2014):3467-3473.
Files in This Item:
File Name/Size DocType Version Access License
The Effect of the Ra(772KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Huang, Shengshi]'s Articles
[Yu, Hongwei]'s Articles
[Han, Jian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Huang, Shengshi]'s Articles
[Yu, Hongwei]'s Articles
[Han, Jian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Huang, Shengshi]'s Articles
[Yu, Hongwei]'s Articles
[Han, Jian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: The Effect of the Ratio of [M(B plus P)] on the Configuration of Anionic Groups Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2).pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.