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题名: The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)
作者: Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping; Yang, Zhihua; Wang, Xian
通讯作者: Han, J
关键词: Synthesis design ; Chain structures ; Borates ; Phosphates ; Lead
刊名: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
发表日期: 2014
DOI: 10.1002/ejic.201402389
期: 22, 页:3467-3473
收录类别: SCI
摘要: Compounds containing both B-O and P-O groups are of wide interest and have been classified into borophosphates and borate-phosphates by R. Kniep et al. In addition to the B/P ratio, analysis results show that regulating the [M/(B+P)] ratio is also an effective strategy to synthesize new borate-phosphates. The first lithium lead borate-phosphate, LiPb4(BO3)(PO4)(2), was synthesized by regulating this ratio. This compound crystallizes in the orthorhombic space group Pbca (No. 61). It possesses a 3D structure with a corrugated 2D layer of [B2Pb8O18] that is further connected by a [LiP2O8] chain; both BO3 and PO4 were isolated. First-principle theoretical studies were performed to aid the understanding of the electronic structures and the linear optical properties. In addition, thermal analysis, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy were performed on the reported material.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3755
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Huang, Shengshi,Yu, Hongwei,Han, Jian,et al. The Effect of the Ratio of [M/(B plus P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2014(22):3467-3473.
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文件名: The Effect of the Ratio of [M(B plus P)] on the Configuration of Anionic Groups Synthesis of the Borate-Phosphate LiPb4(BO3)(PO4)(2).pdf
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