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Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)]
Guo, Yanan; Qiu, Yuchen; Li, Jiyang; Shao, Lang; Song, Xiaowei
2014
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
Volume47Issue:47Pages:99-101
AbstractA new open-framework aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)] (denoted as FeAPO-CJ51), with mixed-valence iron (II, III) has been hydrothermally synthesized by using piperazine as the template. The three-dimensional framework of FeAPO-CJ51 is constructed by the connection of metal-centered MOn (M = Fe/Al, n = 4, 5, 6) polyhedra and PO4 tetrahedra, which contains interconnecting 8-ring channels along the [010] and [001] directions. Diprotonated piperazine cations locate in the 8-ring channels to compensate the negative charge of the anionic framework. Mossbauer and magnetic susceptibility measurements show that equal amounts of Fe2+ and Fe3+ are present in FeAPO-CJ51, which undergo the long-range antiferromagnetic interactions.
KeywordOpen Framework Aluminophosphate Iron Mixed-valence
DOI10.1016/j.inoche.2014.07.026
Indexed BySCI
WOS IDWOS:000341903800025
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3742
Collection环境科学与技术研究室
AffiliationJilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Guo, Yanan,Qiu, Yuchen,Li, Jiyang,et al. Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)][J]. INORGANIC CHEMISTRY COMMUNICATIONS,2014,47(47):99-101.
APA Guo, Yanan,Qiu, Yuchen,Li, Jiyang,Shao, Lang,&Song, Xiaowei.(2014).Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)].INORGANIC CHEMISTRY COMMUNICATIONS,47(47),99-101.
MLA Guo, Yanan,et al."Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)]".INORGANIC CHEMISTRY COMMUNICATIONS 47.47(2014):99-101.
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