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题名: Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)]
作者: Guo, Yanan; Qiu, Yuchen; Li, Jiyang; Shao, Lang; Song, Xiaowei
关键词: Open framework ; Aluminophosphate ; Iron ; Mixed-valence
刊名: INORGANIC CHEMISTRY COMMUNICATIONS
发表日期: 2014
DOI: 10.1016/j.inoche.2014.07.026
卷: 47, 期:47, 页:99-101
收录类别: SCI
摘要: A new open-framework aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)] (denoted as FeAPO-CJ51), with mixed-valence iron (II, III) has been hydrothermally synthesized by using piperazine as the template. The three-dimensional framework of FeAPO-CJ51 is constructed by the connection of metal-centered MOn (M = Fe/Al, n = 4, 5, 6) polyhedra and PO4 tetrahedra, which contains interconnecting 8-ring channels along the [010] and [001] directions. Diprotonated piperazine cations locate in the 8-ring channels to compensate the negative charge of the anionic framework. Mossbauer and magnetic susceptibility measurements show that equal amounts of Fe2+ and Fe3+ are present in FeAPO-CJ51, which undergo the long-range antiferromagnetic interactions.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3742
Appears in Collections:环境科学与技术研究室_期刊论文

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作者单位: Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China

Recommended Citation:
Guo, Yanan,Qiu, Yuchen,Li, Jiyang,et al. Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)][J]. INORGANIC CHEMISTRY COMMUNICATIONS,2014,47(47):99-101.
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文件名: Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)] .pdf
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