| Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)] | |
| Guo, Yanan; Qiu, Yuchen; Li, Jiyang; Shao, Lang; Song, Xiaowei | |
| 2014 | |
| 发表期刊 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| ISSN | 1387-7003 |
| 卷号 | 47期号:47页码:99-101 |
| 摘要 | A new open-framework aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)] (denoted as FeAPO-CJ51), with mixed-valence iron (II, III) has been hydrothermally synthesized by using piperazine as the template. The three-dimensional framework of FeAPO-CJ51 is constructed by the connection of metal-centered MOn (M = Fe/Al, n = 4, 5, 6) polyhedra and PO4 tetrahedra, which contains interconnecting 8-ring channels along the [010] and [001] directions. Diprotonated piperazine cations locate in the 8-ring channels to compensate the negative charge of the anionic framework. Mossbauer and magnetic susceptibility measurements show that equal amounts of Fe2+ and Fe3+ are present in FeAPO-CJ51, which undergo the long-range antiferromagnetic interactions. |
| 关键词 | Open Framework Aluminophosphate Iron Mixed-valence |
| DOI | 10.1016/j.inoche.2014.07.026 |
| 收录类别 | SCI |
| WOS记录号 | WOS:000341903800025 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.xjipc.cas.cn/handle/365002/3742 |
| 专题 | 环境科学与技术研究室 |
| 作者单位 | Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Yanan,Qiu, Yuchen,Li, Jiyang,et al. Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)][J]. INORGANIC CHEMISTRY COMMUNICATIONS,2014,47(47):99-101. |
| APA | Guo, Yanan,Qiu, Yuchen,Li, Jiyang,Shao, Lang,&Song, Xiaowei.(2014).Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)].INORGANIC CHEMISTRY COMMUNICATIONS,47(47),99-101. |
| MLA | Guo, Yanan,et al."Synthesis and characterization of a new open-framework mixed-valence aluminum-iron phosphate (C4H12N2)(2)[Fe2Al5(PO4)(8)(H2O)]".INORGANIC CHEMISTRY COMMUNICATIONS 47.47(2014):99-101. |
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| Synthesis and charac（602KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
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