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题名: Structural insights for the design of new borate-phosphates: synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4)
作者: Wang, Ying; Pan, Shilie; Huang, Shengshi; Dong, Lingyun; Zhang, Min; Han, Shujuan; Wang, Xian
通讯作者: Pan, SL
刊名: Dalton Transactions
发表日期: 2014
DOI: 10.1039/c4dt01199f
卷: 43, 期:34, 页:12886-12893
收录类别: SCI
摘要: Two new metal borate-phosphates, Pb4O(BO3)(PO 4) (1) and Bi4O3(BO3)(PO 4) (2), have been successfully designed and synthesized. The structures of the title compounds were determined by single-crystal X-ray diffraction. The title compounds have similar crystal structures consisting of oxygen-centered (OPb4) or (OBi4) tetrahedra as well as isolated BO3 and PO4 groups. Structural comparison and the Madelung energy calculation indicate that the title compounds also exhibit a strong correlation with the known metal borates and phosphates. In addition, a strategy of BO3-PO4 substitution is proposed for designing new borate-phosphates. Thermal analyses, IR spectroscopy and UV-vis-NIR diffuse reflectance spectroscopy have also been performed
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3738
Appears in Collections:中国科学院特殊环境功能材料与器件重点试验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Being 100049, Peoples R China

Recommended Citation:
Wang, Ying,Pan, Shilie,Huang, Shengshi,et al. Structural insights for the design of new borate-phosphates: synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4)[J]. Dalton Transactions,2014,43(34):12886-12893.
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文件名: Structural insights for the design of new borate-phosphates synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4).pdf
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