Structural insights for the design of new borate-phosphates: synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4)
Wang, Ying; Pan, Shilie; Huang, Shengshi; Dong, Lingyun; Zhang, Min; Han, Shujuan; Wang, Xian; Pan, SL
2014
Source PublicationDalton Transactions
ISSN14779226
Volume43Issue:34Pages:12886-12893
AbstractTwo new metal borate-phosphates, Pb4O(BO3)(PO 4) (1) and Bi4O3(BO3)(PO 4) (2), have been successfully designed and synthesized. The structures of the title compounds were determined by single-crystal X-ray diffraction. The title compounds have similar crystal structures consisting of oxygen-centered (OPb4) or (OBi4) tetrahedra as well as isolated BO3 and PO4 groups. Structural comparison and the Madelung energy calculation indicate that the title compounds also exhibit a strong correlation with the known metal borates and phosphates. In addition, a strategy of BO3-PO4 substitution is proposed for designing new borate-phosphates. Thermal analyses, IR spectroscopy and UV-vis-NIR diffuse reflectance spectroscopy have also been performed
DOI10.1039/c4dt01199f
Indexed BySCI
WOS IDWOS:000341064100011
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3738
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Being 100049, Peoples R China
Recommended Citation
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Wang, Ying,Pan, Shilie,Huang, Shengshi,et al. Structural insights for the design of new borate-phosphates: synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4)[J]. Dalton Transactions,2014,43(34):12886-12893.
APA Wang, Ying.,Pan, Shilie.,Huang, Shengshi.,Dong, Lingyun.,Zhang, Min.,...&Pan, SL.(2014).Structural insights for the design of new borate-phosphates: synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4).Dalton Transactions,43(34),12886-12893.
MLA Wang, Ying,et al."Structural insights for the design of new borate-phosphates: synthesis, crystal structure and optical properties of Pb4O(BO3)(PO4) and Bi4O3(BO3)(PO4)".Dalton Transactions 43.34(2014):12886-12893.
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