Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa2(B3O6)(2)
Li, Hongyi; Dong, Lingyun; Lu, Yi; Pan, Shilie; Lu, Xiaoquan; Yu, Hongwei; Wu, Hongping; Su, Xin; Yang, Zhihua
2014
发表期刊Journal of Alloys and Compounds
ISSN0925-8388
卷号615期号:12页码:561-565
摘要

A new lead barium borate, PbBa2(B3O6) 2, has been synthesized by the standard solid-state reaction at temperature in the range 700-750 °C. The crystal structure has been determined by single crystal X-ray diffraction. PbBa2(B 3O6)2 crystallizes in the rhombohedral space group R3¯ with unit cell a = 7.2056(8) A˚, c = 18.752(6) A˚, and Z = 3. The nearly planar B3O6 groups serve as the fundamental building units, which are distributed layer upon layer perpendicular to the c axis. Regular PbO6 octahedra and irregular BaO9 polyhedra alternately locate between the B3O6 layers. DSC curve and the powder X-ray diffraction pattern of melted PbBa2(B 3O6)2 illustrate that PbBa2(B 3O6)2 melts incongruently. The IR spectrum further proves the presence of BO3 groups. The calculated band structures of PbBa2(B3O6)2 and the density of states have also been investigated.

关键词Crystal Structure Solid-state Reaction Pbba2(B3o6)(2) X-ray Diffraction
DOI10.1016/j.jallcom.2014.06.187
收录类别SCI
WOS记录号WOS:000342245700087
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3732
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
作者单位1.Qual Prod Supervis & Inspect Inst Technol, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Beijing Univ Chem Technol, Coll Sci, Beijing 100029, Peoples R China
推荐引用方式
GB/T 7714
Li, Hongyi,Dong, Lingyun,Lu, Yi,et al. Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa2(B3O6)(2)[J]. Journal of Alloys and Compounds,2014,615(12):561-565.
APA Li, Hongyi.,Dong, Lingyun.,Lu, Yi.,Pan, Shilie.,Lu, Xiaoquan.,...&Yang, Zhihua.(2014).Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa2(B3O6)(2).Journal of Alloys and Compounds,615(12),561-565.
MLA Li, Hongyi,et al."Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa2(B3O6)(2)".Journal of Alloys and Compounds 615.12(2014):561-565.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Synthesis, crystal s(905KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Li, Hongyi]的文章
[Dong, Lingyun]的文章
[Lu, Yi]的文章
百度学术
百度学术中相似的文章
[Li, Hongyi]的文章
[Dong, Lingyun]的文章
[Lu, Yi]的文章
必应学术
必应学术中相似的文章
[Li, Hongyi]的文章
[Dong, Lingyun]的文章
[Lu, Yi]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa2(B3O6)(2).pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。