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2-乙酰基-6-三甲基硅基苯基三氟甲磺酸酯的合成
Alternative TitleSynthesis of 2-Acetyl-6-(trimethylsilyl) phenyl Trifluoromethanesulfonate
孙银蕾; 刘波
2014
Source Publication合成化学
ISSN1005-1511
Volume22Issue:3Pages:395-397,400
Abstract以2-三甲基硅基苯酚为原料,经甲酰化、酯化、亲核加成和氧化反应首次合成了3-乙酰基苯炔的前体——2-乙酰基-6-三甲基硅基苯基三氟甲磺酸酯,总收率35%,其结构经1H NMR和13C NMR确证.
Other Abstract2-Acetyl-6-(trimethylsilyl)phenyl trifluoromethanesulfonate in total yield of 35% was synthesized from 2-(trimethylsilyl)phenol by formylation, esterification, nucleophilic addition of methyl Grignard reagent to carbonyl group and further oxidation of the resulting benzylic alcohol for the first time. The structure was confirmed by ~1H NMR and ~(13)C NMR.
Keyword2-三甲基硅基苯酚 2-乙酰基-6-三甲基硅基苯基三氟甲磺酸酯 3-乙酰基苯炔前体 密旋霉素 合成 2-(Trimethylsilyl) Phenol 2-acetyl-6-(Trimethylsilyl) Phenyl Trifluoromethanesulfonate 3-acetyl Aryne Precursor Pactamycin Synthesis
DOI10.15952/j.cnki.cjsc.2014.03.022
Indexed ByCSCD
CSCD IDCSCD:5165136
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/3690
Collection资源化学研究室
Affiliation中国科学院新疆理化技术研究所;中国科学院大学
Recommended Citation
GB/T 7714
孙银蕾,刘波. 2-乙酰基-6-三甲基硅基苯基三氟甲磺酸酯的合成[J]. 合成化学,2014,22(3):395-397,400.
APA 孙银蕾,&刘波.(2014).2-乙酰基-6-三甲基硅基苯基三氟甲磺酸酯的合成.合成化学,22(3),395-397,400.
MLA 孙银蕾,et al."2-乙酰基-6-三甲基硅基苯基三氟甲磺酸酯的合成".合成化学 22.3(2014):395-397,400.
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