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题名: Effect of pH on PCP remediation by smectite supported Pd<sup>0</sup>/Fe<sup>0</sup>
作者: HanJunli ; JiaHanzhong ; SongCunyi
会议名称: 2012 International Conference on Sustainable Energy and Environmental Engineering, ICSEEE 2012
会议日期: December 29, 2012 - December 30, 2012
出版日期: 2013
会议地点: Guangzhou, China
通讯作者: Han, J.(hjlbt@126.com)
出版地: Trans Tech Publications, P.O. Box 1254, Clausthal-Zellerfeld, D-38670, Germany
收录类别: EI
ISSN: 16609336
ISBN: 9783037856499
部门归属: (1) College of civil and environmental engineering, University of science and technology Beijing, Beijing, China
摘要: Due to its influence on iron corrosion and involvement in dechlorination reaction, the concentration of H+ (i.e. reaction pH) is crucial to the reactivity and efficiency of nanosized Pd0/Fe0. In this study, PCP dechlorination by smectite-templated Pd0/Fe0 was studied and the effect of pH on PCP dechlorination was investigated in detail. The reaction rate constant is critically dependant on the reaction pH over the range 6.0~10.0. When the pH is 6.0~8.0, the dechlorination rate constant (kobs) increases rapidly with decreasing the reaction pH value; the rate change is up to 3.346 folds with decreasing of per pH unit; while it decreases down to 0.3338 when pH is in the range 8.0~10.0. The reductive efficiency of zero-valent iron (ZVI) was further investigated by spiking excess PCP in the reaction system. The maximal reaction efficiency of ZVI for PCP dechlorination attains to 78% when pH is 9.0. The difference between the dechlorination rate and reductive efficiency with respect to reaction pH suggest that ZVI could not be effectively utilized to reduce PCP under acidic condition.
语种: 英语
内容类型: 会议论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/3622
Appears in Collections:环境科学与技术研究室_会议论文

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