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Preparation and characterization of NTC NiMn2O4-La1-xCaxMnO3 (0&lex&le0.3) composite ceramics
ZhangHui Min; GuanFang; ChangAi Min; ZhaoLi Jun
2013
会议名称2013 2nd International Conference on Materials Science and Technology, ICMST 2013
页码78-83
会议日期April 11, 2013 - April 12, 2013
会议地点Hong Kong, China
出版地Trans Tech Publications Ltd, Kreuzstrasse 10, Zurich-Durnten, CH-8635, Switzerland
摘要

Composite ceramics made of spinel structure NiMn2O4 and CaO-doped perovskite structure LaMnO3 were prepared by a conventional solid state reaction and sintered at different temperatures. The XRD patterns have shown that the major phases presented in the sintered samples are NiMn2O4 compounds with the spinel structure, La1-xCaxMnO3 with the perovskite structure and NiO with a monoclinic structure. SEM images show that the density and grain size of the composite ceramics increases with sintered temperature increasing. The electrical resistivity of the composite ceramics at 25 °C is found to change significantly depending on the CaO content, while the thermal constant B is still reasonably large in the range of 2400 to 3000 K. For the composition x = 0.1, the composite with a low electrical resistivity (ρ25 °C=4.46 ω · cm) and moderate B value (B25/50=2762K) was obtained. These composites could be applied as potential candidates for NTC thermistors in the suppression of the inrush current

收录类别EI
文献类型会议论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/3621
专题材料物理与化学研究室
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ZhangHui Min,GuanFang,ChangAi Min,et al. Preparation and characterization of NTC NiMn2O4-La1-xCaxMnO3 (0&lex&le0.3) composite ceramics[C]. Trans Tech Publications Ltd, Kreuzstrasse 10, Zurich-Durnten, CH-8635, Switzerland,2013:78-83.
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