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学科主题: Chemistry ; Electrochemistry ; Energy & Fuels
题名: enhanced electrocatalytic performance for methanol oxidation on pt-tio2/ito electrode under uv illumination
作者: Zhang Hongmei; Zhou Weiqiang; Du Yukou; Yang Ping; Wang Chuanyi; Xu Jingkun
关键词: Methanol ; Electrooxidation ; UV illumination ; Pt nanoparticles ; Titanium oxide
刊名: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
发表日期: 2010
DOI: 10.1016/j.ijhydene.2010.09.025
卷: 35, 期:24, 页:13290-13297
收录类别: SCI
资助者: National Natural Science Foundation of China 51073114, 20933007; Foundation of Jiangsu Province Education Committee 08KJD150020; Soochow University
摘要: Pt is one of the most important electrode materials employed in direct methanol fuel cell, and many efforts have been directed to improving its electrocatalytic performance. In this work, Pt-TiO2 nanocomposites are successfully prepared by a sol-gel method. As revealed by TEM, Pt nanoparticles with an average size of 2.6 nm are well uniformly dispersed on porous TiO2. XRD structural characterization indicates that Pt possesses a face centered cubic crystal structure while TiO2 is in the format of both rutile and anatase phases. The electrochemical performance of as-prepared nanocomposite electrode (Pt-TiO2/ITO) is evaluated by studying the electrocatalytic oxidation of methanol in an alkaline medium with or without UV illumination. Comparative experiments evince that the electrochemical performance of Pt-TiO2/ITO for methanol electrooxidation is markedly improved under UV illumination. Under UV illumination, moreover, the poisoning resistance of Pt-TiO2/ITO for methanol electrooxidation is significantly improved, as supported by the results of time-coursed current measurements. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2816
Appears in Collections:环境科学与技术研究室_期刊论文

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作者单位: Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Tufts Univ, Dept Chem, Medford, MA 02155 USA;Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China

Recommended Citation:
Zhang Hongmei,Zhou Weiqiang,Du Yukou,et al. enhanced electrocatalytic performance for methanol oxidation on pt-tio2/ito electrode under uv illumination[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(24):13290-13297.
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