Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O
Zhao Yi; Pan Shilie; Li Feng; Wang Yongjiang; Fan Xiaoyun; Dong Xiaoyu; Jia Dianzeng; Guo Jixi; Zhou Zhongxiang
2011
发表期刊SOLID STATE SCIENCES
ISSN1293-2558
卷号13期号:1页码:82-87
摘要

Rb-4[B4O5(OH)(4)]2 center dot 3H(2)O has been grown by slow evaporation method with crystal sizes up to 11 mm x 7 mm x 4 mm. Its crystal structure has been determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (XRD). IR, and TGA. It crystallizes in the orthorhombic space group Pbcn, with a = 16.3984(14) angstrom, b = 7.7850(7) angstrom, c = 16.0763(16) angstrom, and Z = 4. It contains isolated [B4O5(OH)(4)](2-) polyanions, free water molecules and Rb cations. The Rb(1) and Rb(2) atoms are coordinated by nine and ten oxygen atoms, respectively. Connections between isolated [B4O5(OH)(4)](2-) polyanions are provided by Rb polyhedra and the hydrogen-bonding to form a three-dimensional network.

关键词Rb-4b4o5(Oh)(4)(2)Center Dot 3h(2)o Borate Crystal Structure Crystal Growth
学科领域Chemistry ; Physics
DOI10.1016/j.solidstatesciences.2010.10.013
收录类别SCI
WOS记录号WOS:000287286000013
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/2811
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
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Zhao Yi,Pan Shilie,Li Feng,et al. Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O[J]. SOLID STATE SCIENCES,2011,13(1):82-87.
APA Zhao Yi.,Pan Shilie.,Li Feng.,Wang Yongjiang.,Fan Xiaoyun.,...&Zhou Zhongxiang.(2011).Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O.SOLID STATE SCIENCES,13(1),82-87.
MLA Zhao Yi,et al."Synthesis, structure, and properties of a novel hydrated borate Rb-4[B4O5(OH)(4)](2)center dot 3H(2)O".SOLID STATE SCIENCES 13.1(2011):82-87.
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