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学科主题: Chemistry ; Materials Science
题名: A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10
作者: Yang Yun; Pan Shilie; Hou Xueling; Wang Chuanyi; Poeppelmeier Kenneth R.; Chen Zhaohui; Wu Hongping; Zhou Zhongxiang
通讯作者: Pan, SL
刊名: JOURNAL OF MATERIALS CHEMISTRY
发表日期: 2011
DOI: 10.1039/c0jm03187a
卷: 21, 期:9, 页:2890-2894
收录类别: SCI
资助者: National Natural Science Foundation of China 50802110; Chinese Academy of Sciences; Western Light Joint Scholar Foundation of Chinese Academy of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 200816120; National Science Foundation DMR-0604454
摘要: Single crystals of Li3Cs2B5O10 have been synthesized and its structure determined by single-crystal X-ray diffraction. Li3Cs2B5O10 crystallizes in the non-centrosymmetric space group C222(1) ( No. 20). The structure consists of isolated B5O10 groups that are bridged by LiOn (n = 4, 5) and CsOn (n = 8, 10) polyhedra through their vertex oxygen atoms to form an infinite three-dimensional structure. Li3Cs2B5O10 melts congruently and exhibits a short-wavelength absorption onset at 175 nm. As-prepared Li3Cs2B5O10 is both non-centrosymmetric and phase matchable as supported by second harmonic generation measurements.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/2810
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

Recommended Citation:
Yang Yun,Pan Shilie,Hou Xueling,et al. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(9):2890-2894.
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