A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10
Yang Yun; Pan Shilie; Hou Xueling; Wang Chuanyi; Poeppelmeier Kenneth R.; Chen Zhaohui; Wu Hongping; Zhou Zhongxiang
2011
Source PublicationJOURNAL OF MATERIALS CHEMISTRY
ISSN0959-9428
Volume21Issue:9Pages:2890-2894
Abstract

Single crystals of Li3Cs2B5O10 have been synthesized and its structure determined by single-crystal X-ray diffraction. Li3Cs2B5O10 crystallizes in the non-centrosymmetric space group C222(1) ( No. 20). The structure consists of isolated B5O10 groups that are bridged by LiOn (n = 4, 5) and CsOn (n = 8, 10) polyhedra through their vertex oxygen atoms to form an infinite three-dimensional structure. Li3Cs2B5O10 melts congruently and exhibits a short-wavelength absorption onset at 175 nm. As-prepared Li3Cs2B5O10 is both non-centrosymmetric and phase matchable as supported by second harmonic generation measurements.

Subject AreaChemistry ; Materials Science
DOI10.1039/c0jm03187a
Indexed BySCI
WOS IDWOS:000287369300016
Citation statistics
Cited Times:78[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/2810
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
资源化学研究室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
Recommended Citation
GB/T 7714
Yang Yun,Pan Shilie,Hou Xueling,et al. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(9):2890-2894.
APA Yang Yun.,Pan Shilie.,Hou Xueling.,Wang Chuanyi.,Poeppelmeier Kenneth R..,...&Zhou Zhongxiang.(2011).A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10.JOURNAL OF MATERIALS CHEMISTRY,21(9),2890-2894.
MLA Yang Yun,et al."A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10".JOURNAL OF MATERIALS CHEMISTRY 21.9(2011):2890-2894.
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